in diethyl ether; dichloromethane byproducts: Hg-halocomplexes; addn. of stoich. amt. HgBr2 (in ether) to Ir-complex (in CH2Cl2), then addn. of excess Bu4NI; not isolated, detd. by UV/VIS and IR spectroscopy;
参考文献
Vecernik, J.; Masek, J.; Vlcek, A. A.
Inorganica Chimica Acta, 1977 , vol. 21, p. 271 - 276
KH in tetrahydrofuran byproducts: H2; borane and THF condensing onto KH and Bu4NI under N2 at -196°C, warming to room temp., stirring for 15 h, THF removing, BBr3 condensing onto the residue at -196°C , warming to room temp., stirring for 6 h; isolated by sublimation; identified by NMR spectrum;
参考文献
Toft, Mark A.; Leach, J. B.; Himpsl, Francis L.; Shore, Sheldon G.
Inorganic Chemistry, 1982 , vol. 21, p. 1952 - 1957
in acetonitrile Kinetics; byproducts: I3(1-), Cl(1-); excess of Bu4NI, in presence of Bu4NClO4, 25-45°C; not isolated, reaction followed by UV/VIS spectroscopy;
参考文献
Peloso, Arnaldo
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1976 , p. 984 - 988
