三丁基[(苯磺酰基)甲基]锡烷合成路线 （共 25 条）
反应条件
in tetrahydrofuran; diethyl ether
byproducts: C6H5S(O)2CH2MgBr; under anaerobic conditions, in NMR tube; Sn compd., Mg compd. (molar ratio 1:1) in Et2O, SnMe4 (internal standard) and THF mixed; reacted for 1 h; not isolated; monitored by (119)Sn NMR spectra; > 95percent conversion;
参考文献
Yousef, Rushdi I; Rueffer, Tobias; Schmidt, Harry; Steinborn, Dirk
Journal of Organometallic Chemistry, 2002 , vol. 655, # 1-2 p. 111 - 114
反应条件
in not given
byproducts: C6H5S(O)2CH2MgI; under anaerobic conditions, in NMR tube; Sn compd., soln. of Mg compd. (molar ratio 1:1), SnMe4 (internal standard) and THF mixed; reacted for 1h; not isolated; monitored by (119)Sn NMR spectra; > 95percent conversion;
参考文献
Yousef, Rushdi I; Rueffer, Tobias; Schmidt, Harry; Steinborn, Dirk
Journal of Organometallic Chemistry, 2002 , vol. 655, # 1-2 p. 111 - 114
反应条件
in tetrahydrofuran
byproducts: C6H5S(O)2CH2MgCl; under anaerobic conditions, in NMR tube; Sn compd., Mg compd. (molar ratio 1:1) in THF, SnMe4 (internal standard) and THF mixed; reacted for 1 h; not isolated; monitored by (119)Sn NMR spectra; > 95percent conversion;
参考文献
Yousef, Rushdi I; Rueffer, Tobias; Schmidt, Harry; Steinborn, Dirk
Journal of Organometallic Chemistry, 2002 , vol. 655, # 1-2 p. 111 - 114
反应条件
2: diethyl ether
View Scheme
参考文献
Gmelin Handbook: Sn: Org.Verb.2, 1.1.2.5.2, page 276 - 305
反应条件
2: tetrahydrofuran
3: C2H5OH
View Scheme
参考文献
Gmelin Handbook: Sn: Org.Verb.2, 1.1.2.5.2, page 276 - 305
