双(1,2-双(二苯基膦)乙烷)钯合成路线 （共 33 条）
反应条件
NaOSiMe3 in tetrahydrofuran; THF-d8 (tetrahydrofuran-d8) under N2; at room temp.; PH(Me)(Ph)(BH3) and o-AnI added to soln. of Pd(dppe)(o-An)(I) in THF; NaOSiMe3 in THF added; soln. mixed; THF-d8 added;react. monitored by 31P NMR for 48 h; not isolated;
参考文献
Organometallics, , vol. 22, # 16 p. 3205 - 3221
反应条件
in dichloromethane Kinetics; byproducts: CH2CH(CH3)CH2CH(COCH3)2; N2, room temp.; N2 satd. soln. of complex filled in quartz cell; addn. of Ph2PC2H4PPh2 soln.; various initial concentrations caused various yields; not isolated; followed course by UV spectroscopy;
参考文献
Organometallics, , vol. 8, p. 1756 - 1760
反应条件
byproducts: PH(CH3)(tBu3C6H2);
参考文献
Journal of the American Chemical Society, , vol. 119, # 21 p. 5039 - 5040
反应条件
in toluene byproducts: P(CH3)(C6H2(CH(CH3)2)3)CH2CHCH2; (N2, at 23°C); Pd complex in toluene added to a soln. of Pt complex, a soln. of C2H4(P(C6H5)2)2 added; not isolated, detected by NMR;
参考文献
Organometallics, , vol. 25, # 22 p. 5435 - 5448
反应条件
in tetrahydrofuran; THF-d8 (tetrahydrofuran-d8) byproducts: C6H5CH2CH2CH2SCH3; to soln. of Pd(CH2CH2CH2C6H5)2(dppe) in THF/THF-d8 (4:1) added CH3SSCH3 at 15°C under Ar, mixture transferred to NMR tube for 6 days; not isolated, identified by NMR;
参考文献
European Journal of Inorganic Chemistry, , # 11 p. 2868 - 2877
反应条件
in tetrahydrofuran; THF-d8 (tetrahydrofuran-d8) byproducts: CH3CH2CH2C6H5; to soln. of Pd(CH2CH2CH2C6H5)2(dppe) in THF/THF-d8 (4:1) added (CH3)2CHSH under Ar, mixture transferred to NMR tube, 6 days at -30°C, 1 day at -15°C, 8 days at 0°C; not isolated, identified by NMR;
参考文献
European Journal of Inorganic Chemistry, , # 11 p. 2868 - 2877
反应条件
in tetrahydrofuran; THF-d8 (tetrahydrofuran-d8) byproducts: CH3CH2CH2C6H5; to soln. of Pd(CH2CH2CH2C6H5)2(dppe) in THF/THF-d8 (4:1) added (CH3)3CSHunder Ar, mixture transferred to NMR tube, 6 days at -30°C, 1 da y at -15°C, 8 days at 0°C; not isolated, identified by NMR;
参考文献
European Journal of Inorganic Chemistry, , # 11 p. 2868 - 2877
反应条件
in tetrahydrofuran; THF-d8 (tetrahydrofuran-d8) byproducts: CH3SeCH2CH2CH2C6H5; to soln. of Pd(CH2CH2CH2C6H5)2(dppe) in THF/THF-d8 (4:1) added (CH3Se)2 at -30°C under Ar, mixture transferred to NMR tube for 2 days; not isolated, identified by NMR;
参考文献
European Journal of Inorganic Chemistry, , # 11 p. 2868 - 2877
反应条件
in tetrahydrofuran under N2, react. at 203 K; not isolated, identified by (31)P-NMR;
参考文献
Polyhedron, , vol. 12, p. 721 - 730
反应条件
in tetrahydrofuran under N2, react. at room temp.; not isolated, identified by (31)P-NMR;
参考文献
Polyhedron, , vol. 12, p. 721 - 730
