hydrogenchloride; lithium aluminium tetrahydride in benzene Kinetics; introduction of HCl gas into a soln. of HSi(SiCl3)3 and a very few trimethylamine, at room temp.; detection by Raman and (1)H-NMR;

hydrogenchloride; lithium aluminium tetrahydride in benzene Kinetics; introduction of HCl gas into a soln. of Si5Cl12 and a very few trimethylamine, at room temp.; detection by Raman and (1)H-NMR;

byproducts: CH2Cl2; copyrolysis (1:1), quartz tube (550°C, yields of products depending on temperature (350 to 600°C)), product condensing; products not isolated, reaction monitoring by mass spectroscopy;

copyrolysis (1percent CHCl3), quartz tube (575°C, retention time 30 s, yields of products depending on temperature (350 to 600°C)), product condensing; products not isolated, reaction monitoring by mass spectroscopy;

byproducts: 1,1-dichloro-1-silacyclopent-3-ene, 1-chloro-1-silacyclopent-3-ene; copyrolysis, quartz tube (560°C, retention time 30 s, yields of products depending on temperature (350 to 600°C)), product condensing; products not isolated, reaction monitoring by mass spectroscopy;