acrylic acid n-butyl ester; anhydrous lithium acetate; copper diacetate; palladium diacetate in N,N-dimethyl-formamide byproducts: butyl 3-(4-methylphenyl)propenoate; under Ar; 0.30-0.36 mmol of organotin comp. and 0.30 mmol of olefin added to a soln. of 0.03 mmol of Pd(OAc)2, 0.90 mmol of Cu(OAc)2 and 0.60 mmol of LiOAc in DMF at room temp., mixt. stirred at 100° for 24 h, diluted with Et2O; monitored by NMR spectra;
参考文献
Hirabayashi, Kazunori; Ando, Jun-Ichi; Kawashima, Jun; Nishihara, Yasushi; Mori, Atsunori; Hiyama, Tamejiro
Bulletin of the Chemical Society of Japan, 2000 , vol. 73, # 6 p. 1409 - 1417
in tetrahydrofuran byproducts: p-tolylboronic acid; to srirred soln. of Sn-compound in THF was added soln. of BH3 in THF under N2, mixt. was left at room temp. for 1 h, refluxed for 1 h, cooled, Et2O and water was added; dried with MgSO4, solvent was removed under vac., column chromy. on silica gel with hexane and hexane-Et2O, recrystd. from water;
参考文献
Faraoni; Koll; Mandolesi; Zuniga; Podesta
Journal of Organometallic Chemistry, 2000 , vol. 613, # 2 p. 236 - 238
