甲基-4,6-O-亚苄基-Α-D-吡喃葡糖苷合成路线 （共 91 条）
反应条件
1.1: NaH / dimethylformamide / 2 h / 20 °C 1.2: 88 percent / dimethylformamide / 12 h / 20 °C 2.1: BH3*Me2S / CH2Cl2 / 3 h / 20 °C 2.2: 68 percent / BF3*OEt2 / CH2Cl2 / 0.5 h / 20 °C View Scheme
参考文献
Mondon, Martine; Lecornue, Frederic; Guillard, Jerome; Nakagawa, Shinpei; Kato, Atsushi; Bleriot, Yves
Bioorganic and Medicinal Chemistry, 2013 , vol. 21, # 16 p. 4803 - 4812
反应条件
pyridine in dichloromethane Ambient temperature;
参考文献
Rodriguez, Evelyn B.; Stick, Robert V.
Australian Journal of Chemistry, 1990 , vol. 43, # 4 p. 665 - 679
反应条件
pyridine Ambient temperature;
参考文献
Smith III, Amos B.; Hale, Karl J.; Vaccaro, Henry A.; Rivero, Ralph A.
Journal of the American Chemical Society, 1991 , vol. 113, # 6 p. 2112 - 2122
反应条件
1: Me-4,6-(Bz)-α-D-glcp With pyridine in 1,2-dichloro-ethane T=20°C; 1 h; 2: benzoyl chloride in 1,2-dichloro-ethane T=20°C;
参考文献
Synlett, , # 12 p. 2191 - 2193
反应条件
1: sodium periodate / water; methanol / 20 h / 5 - 20 °C / |Darkness 2: 80 °C View Scheme
参考文献
Franconetti, Antonio; Borrachero, Pastora; Gomez-Guillen, Manuel; Cabrera-Escribano, Francisca
Synlett, 2013 , vol. 24, # 2 art. no. ST-2012-D0925-L, p. 249 - 253
反应条件
1: With sodium hydride in N,N-dimethyl-formamide 1 h; 2: With 1-(toluene-p-sulphonyl)imidazole in N,N-dimethyl-formamide T=20°C; 2 h;
参考文献
Rapi, Zsolt; Bako, Peter; Keglevich, Gyoergy; Szoellsy, Aron; Drahos, Laszlo; Hegeds, Laszlo
Carbohydrate Research, 2013 , vol. 365, p. 61 - 68
反应条件
p-toluenesulfonyl chloride; tetra(n-butyl)ammonium hydrogensulfate
参考文献
Carbohydrate Research, , vol. 183, p. 135 - 139
反应条件
1: With sodium hydride in N,N-dimethyl-formamide 1 h; 2: With 1-(toluene-p-sulphonyl)imidazole in N,N-dimethyl-formamide T=20°C; 2 h;
参考文献
Rapi, Zsolt; Bako, Peter; Keglevich, Gyoergy; Szoellsy, Aron; Drahos, Laszlo; Hegeds, Laszlo
Carbohydrate Research, 2013 , vol. 365, p. 61 - 68
反应条件
p-toluenesulfonyl chloride; tetra(n-butyl)ammonium hydrogensulfate
参考文献
Szeja, Wieslaw
Carbohydrate Research, 1988 , vol. 183, p. 135 - 139
反应条件
N-ethyl-N,N-diisopropylamine in chloroform T=-40°C; 4 h; Reagent/catalystTemperatureSolvent; regioselective reaction;
参考文献
Allen, C. Liana; Miller, Scott J.
Organic Letters, 2013 , vol. 15, # 24 p. 6178 - 6181
