triphenylphosphine in benzene (N2); Rh complex and phosphinederiv. (1/1 mol) was reacted in C6H6 (or C6D6); not isolated, detected by (1)H- and (31)P-NMR;
参考文献
Burgess, Kevin; Van Der Donk, Wilfred A.; Westcott, Stephen A.; Marder, Todd B.; Baker, R. Thomas; Calabrese, Joseph C.
Journal of the American Chemical Society, 1992 , vol. 114, # 24 p. 9350 - 9359
P(C6H5)3 in THF-d8 (tetrahydrofuran-d8) addn. of 3 equiv. of PPh3 to soln. of Rh-complex (25°C, NMR tube), (31)P-NMR monitoring at -40°C; not isolated;
参考文献
Burgess, Kevin; Van Der Donk, Wilfred A.; Westcott, Stephen A.; Marder, Todd B.; Baker, R. Thomas; Calabrese, Joseph C.
Journal of the American Chemical Society, 1992 , vol. 114, # 24 p. 9350 - 9359
in methanol byproducts: C6H5CH((CH3)2C3HN2)2; soln. was stirred at room temp. for 18 h under N2; ppt. filtered off, washed with methanol, filtrate evapd. washed with hexane;
参考文献
Leung, Ping Y.; Peterson, Louis K.
Journal of Organometallic Chemistry, 1981 , vol. 219, # 3 p. 409 - 420
