triethylamine in benzene byproducts: (C2H5)3NHCl; Et3N adding in excess to germane soln. in benzene, stirring at ambient temp., Et3NHCl filtering off, ligand adding, heating in a sealed tube for 3 h at 100°C;
参考文献
Riviere, P.; Castel, A.; Satge, J.
Journal of Organometallic Chemistry, 1982 , vol. 232, # 2 p. 123 - 136
2,2'-azo-bisisobutyronitrile in neat (no solvent) trigermane and an excess of disulfide heating for 2.5 h at 100°Cin the presence of AIBN in a sealed tube; isolated by distillation;
参考文献
Riviere, P.; Castel, A.; Satge, J.; Guyot, D.
Journal of Organometallic Chemistry, 1984 , vol. 264, # 1-2 p. 193 - 206
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反应条件
in benzene-d6 byproducts: CO; Irradiation (UV/VIS); irradiation (high-pressure lamp Hanau TQ 150) for 2.5 h (Ar); not isolated; GLC, (1)H-NMR;
参考文献
Castel, A.; Riviere, P.; Ahbala, M.; Satge, J.; Soufiaoui, M.; Knouzi, N.
Journal of Organometallic Chemistry, 1993 , vol. 447, # 1 p. 123 - 130
in neat (no solvent) Irradiation (UV/VIS); Ge deriv. and a large excess of organic reagent irradiating in a quartztube for 4 h then concg. in vacuo; identified by high-pressure chromy. and NMR spectra;
参考文献
Riviere, P.; Castel, A.; Satge, J.; Guyot, D.
Journal of Organometallic Chemistry, 1984 , vol. 264, # 1-2 p. 193 - 206
