3,3,3,-三氟-2-(三氟甲基)-1,2-氧化丙烯合成路线 （共 13 条）
反应条件
in tetrahydrofuran
T=25°C; 48 h;
参考文献
Grushin, Vladimir V.; Marshall, William J.; Halliday, Gary A.; Davidson, Fredric; Petrov, Viacheslav A.
Journal of Fluorine Chemistry, 2002 , vol. 117, # 2 p. 121 - 129
反应条件
hydrogen bromide
3 h; Heating;
参考文献
Grushin, Vladimir V.; Marshall, William J.; Halliday, Gary A.; Davidson, Fredric; Petrov, Viacheslav A.
Journal of Fluorine Chemistry, 2002 , vol. 117, # 2 p. 121 - 129
反应条件
1: 1,1-bis(trifluoromethyl)-2-bromoethanol With n-butyllithium in diethyl ether; hexane
T=-78°C;
2: 3,3,3-trifluoro-2-(trifluoromethyl)-1,2-propenoxide in diethyl ether; hexane
T=-78 - -10°C; 2 h;
参考文献
Grushin, Vladimir V.; Marshall, William J.; Halliday, Gary A.; Davidson, Fredric; Petrov, Viacheslav A.
Journal of Fluorine Chemistry, 2002 , vol. 117, # 2 p. 121 - 129
