1,2,3,4,5-五氯-6-氟苯合成路线 （共 20 条）
反应条件
potassium fluoride; N,N-dimethyl-formamide T=150°C;
参考文献
Finger; Kruse
Journal of the American Chemical Society, 1956 , vol. 78, p. 6034,6037
反应条件
lt;Cp2Cogt;F in tetrahydrofuran 72 h; Ambient temperature;
参考文献
Bennett, Brian K.; Harrison, Roger G.; Richmond, Thomas G.
Journal of the American Chemical Society, 1994 , vol. 116, # 24 p. 11165 - 11166
反应条件
AlCl3, aluminium chloride; chlorine in 1,2-dichloro-ethane T=5 - 25°C; 5 h;
参考文献
BASF Aktiengesellschaft
Patent: WO2006/111583 A1, 2006 ;
Location in patent: Page/Page column 9 ;
反应条件
AlCl3, aluminium chloride; chlorine in 1,2-dichloro-ethane T=0 - 25°C;
参考文献
BASF Aktiengesellschaft
Patent: WO2006/111583 A1, 2006 ;
Location in patent: Page/Page column 8-9 ;
参考文献
Vorozhtsov,N.N. et al.
J. Gen. Chem. USSR (Engl. Transl.), 1961 , vol. 31, # 5 p. 1674 - 1678,1561 - 1564
反应条件
potassium fluoride in N,N-dimethyl-formamide T=130°C; 1 h; other solvents, times; also in the presence of phase transfer catalysts; Product distribution;
参考文献
Heaton, Alan; Hill, Mark; Drakesmith, Frederick
Journal of Fluorine Chemistry, 1997 , vol. 81, # 2 p. 129 - 132
反应条件
18-crown-6 ether; cesium fluoride in acetonitrile T=80°C; time required to the given yield of monofluoroaromatic compound with various mol ratios, with or without crown ether;
参考文献
Aksenov, V.V.; Vlasov, V.M.; Moryakina, I.M.; Rodionov, P.P.; Fadeeva, V.P.; et al.
Journal of Fluorine Chemistry, 1985 , vol. 28, p. 73 - 88
反应条件
chlorine Irradiation;
参考文献
Vorozhtsov,N.N. et al.
J. Gen. Chem. USSR (Engl. Transl.), 1961 , vol. 31, # 5 p. 1674 - 1678,1561 - 1564
反应条件
(i) Hg(CF3CO2)2, (ii) Cl2; Multistep reaction;
参考文献
Deacon,G.B.; Farquharson,G.J.
Australian Journal of Chemistry, 1977 , vol. 30, p. 1701 - 1713
反应条件
potassium fluoride T=405°C; 15.5 h; C4Cl4N2/KF = 13.4 x 10 E-2, other times, other temperatures, other molar ratios, other fluorinated compounds; Product distribution;
参考文献
Hitzke,J.
Journal of Fluorine Chemistry, 1981 , vol. 17, p. 385 - 402
