1,2,3,4,5-五氯-6-氟苯合成路线 （共 20 条）
反应条件
potassium fluoride T=400°C; 35 h; various temperature, reactant volume, F(1-) ion concentration and contact time; Product distribution;
参考文献
Hitzke, J.
Journal of Fluorine Chemistry, 1980 , vol. 16, p. 103 - 128
反应条件
T=750 - 800°C; 0.00111111 h; flow-type reactor; Product distribution;
参考文献
Ivanova, S. M.; Boikov, Yu. A.; Barabanov, V. G.; V'yunov, K. A.; Ginak, A. I.
Journal of Organic Chemistry USSR (English Translation), 1982 , vol. 18, # 11 p. 2184 - 2185
Zhurnal Organicheskoi Khimii, 1982 , vol. 18, # 11 p. 2463 - 2464
反应条件
T=200°C; Lichtausschluss;
参考文献
Riemschneider
Chemische Berichte, 1958 , vol. 91, p. 2605,2607
反应条件
T=900°C; 0.00105556 h; other temperature, other contact time; Product distributionMechanism;
参考文献
Zemlyanskaya, N. V.; Volkov, G. V.; Barabanov, V. G.; Zenkevich, I. G.; V'yunov, K. A.
J. Gen. Chem. USSR (Engl. Transl.), 1989 , vol. 59, # 3.2 p. 622 - 630,551 - 558
反应条件
potassium fluoride Product distribution / selectivity;
参考文献
BASF Aktiengesellschaft
Patent: WO2006/111583 A1, 2006 ;
Location in patent: Page/Page column 10-11 ;
反应条件
2,4-di-Nitrobenzene; potassium fluoride in 1-methyl-pyrrolidin-2-one T=180°C; P=405.041 Torr; 16 h; Product distribution / selectivity;
参考文献
BASF Aktiengesellschaft
Patent: WO2006/111583 A1, 2006 ;
Location in patent: Page/Page column 10 ;
反应条件
pyridine; sodium hydrogensulfide
参考文献
J. Gen. Chem. USSR (Engl. Transl.), , vol. 35, # 11 p. 2055 - 2062,2046 - 2052
参考文献
Kobrina,L.S.; Yakobson,G.G.
J. Gen. Chem. USSR (Engl. Transl.), 1965 , vol. 35, # 11 p. 2055 - 2062,2046 - 2052
反应条件
1: 88 percent / K2CO3 / 18-crown-6 / acetonitrile / 16 h / Heating
2: 84 percent / BBr3 / CH2Cl2 / 2 h / Heating
View Scheme
参考文献
Kolonko, K. J.; Deinzer, M. L.; Miller, T. L.
Synthesis, 1981 , # 2 p. 133 - 135
反应条件
1: K2CO3 / 18-crown-6 / acetonitrile / Heating; overnight
2: BBr3 / CH2Cl2 / Heating
View Scheme
参考文献
Kolonko, K. J.; Deinzer, M. L.; Miller, T. L.
Synthesis, 1981 , # 2 p. 133 - 135
