(±)-4-溴苯乙烯环氧化物合成路线 (共 33 条)
反应条件
tetrabutylammomium bromide; sodium hydroxide in dichloromethane; water Corey-Chaykovsky reaction; 60 h; Reflux;
参考文献
Cattoen, Xavier; Pericas, Miquel A.
Tetrahedron, 2009 , vol. 65, # 39 p. 8199 - 8205
反应条件
oxone(R); PEG-supported α,α,α-trifluoroacetophenone; sodium hydrogencarbonate in 1,4-dioxane; water T=20°C; 0.0833333 h;
参考文献
Kan, Jovi Tze Wai; Toy, Patrick
Tetrahedron Letters, 2004 , vol. 45, # 33 p. 6357 - 6359
反应条件
sodium hydride in tetrahydrofuran; dimethyl sulfoxide
参考文献
Choi, Matthew Kwok Wai; Toy, Patrick H.
Tetrahedron, 2004 , vol. 60, # 12 p. 2875 - 2879
反应条件
sodium hydroxide in water
参考文献
Journal of Molecular Structure, , vol. 99, p. 259 - 266
反应条件
methyltrioxorhenium (VII); (S,S)-Ph-pybox in dichloromethane T=20°C; 19 h; chemoselective reaction;
参考文献
European Journal of Inorganic Chemistry, , # 36 p. 5972 - 5978
反应条件
1,4-dioxane; anhydrous sodium borate Erwaermen einer Loesung des erhaltenen 2-Brom-1-<4-brom-phenyl>-aethanols in Diisopropylaether mit wss. Kalilauge;
参考文献
Journal of the American Chemical Society, , vol. 76, p. 1631,1634
反应条件
iodosylbenzene; 1-butylpyridinium tetrafluoroborate; [MnIIIT(N-Me-4-Py)P][PF6]5 T=30°C; 4 h; in open air; Title compound not separated from byproducts.;
参考文献
Chemistry Letters, , vol. 36, # 7 p. 848 - 849
反应条件
1-methyl-1H-imidazole; FeCl3·6H2O; dihydrogen peroxide in water; acetone T=25 - 62°C; In air; chemoselective reaction;
参考文献
Green Chemistry, , vol. 13, # 5 p. 1230 - 1237
反应条件
1: trimethyl-oxo-sulfonium iodide With sodium hydride in dimethyl sulfoxide T=0°C; 1 h; Inert atmosphere; 2: 4-bromo-benzaldehyde in dimethyl sulfoxide T=20°C; 3 h; Inert atmosphere;
参考文献
Tetrahedron, , vol. 69, # 18 p. 3669 - 3676
反应条件
1: pyridine 2: NaOH / methanol / 2 h / 20 °C View Scheme
参考文献
Chemical Research in Toxicology, , vol. 11, # 1 p. 44 - 53