1,3-二甲基-2H-苯并咪唑合成路线 （共 16 条）
反应条件
cis-[Ru(dimethyl sulfoxide)4Cl2]; phenyl silane; di-(1-adamantyl)-n-butylphosphine in toluene T=110°C; P=22502.3 Torr; 16 h; AutoclaveInert atmosphere; chemoselective reaction;
参考文献
Li, Yuehui; Fang, Xianjie; Junge, Kathrin; Beller, Matthias
Angewandte Chemie - International Edition, 2013 , vol. 52, # 36 p. 9568 - 9571
Angew. Chem., 2013 , vol. 125, # 36 p. 9747 - 9750,4
反应条件
40percent alkali T=165 - 170°C; 1.5 h;
参考文献
Konstantinchenko, A. A.; Morkovnik, A. S.; Pozharskii, A. F.; Tertov, B. A.
Chemistry of Heterocyclic Compounds (New York, NY, United States), 1985 , vol. 21, # 12 p. 1398 - 1399
Khimiya Geterotsiklicheskikh Soedinenii, 1985 , vol. 21, # 12 p. 1694 - 1695
反应条件
[ruthenium(II)(2,2′:6′,2″-terpyridine)(2,2′-bipyridine)](1+) in acetonitrile-D3 T=24.84°C; Darkness; Kinetics;
参考文献
Matsubara, Yasuo; Fujita, Etsuko; Doherty, Mark D.; Muckerman, James T.; Creutz, Carol
Journal of the American Chemical Society, 2012 , vol. 134, # 38 p. 15743 - 15757,15
反应条件
C56H52Fe2OP4S2 in tetrahydrofuran; acetonitrile T=20°C; 0.333333 h;
参考文献
Wang, Wenguang; Rauchfuss, Thomas B.; Zhu, Lingyang; Zampella, Giuseppe
Journal of the American Chemical Society, 2014 , vol. 136, # 15 p. 5773 - 5782
反应条件
LiOPh; 1,3-dimethyl-1H-benzo[d]imidazol-3-ium iodide in acetonitrile-D3 T=25°C; 28 h; also pyrolysis;
参考文献
Montgrain, France; Ramos, Socorro M.; Wuest, James D.
Journal of Organic Chemistry, 1988 , vol. 53, # 7 p. 1489 - 1492
反应条件
1: 85 percent / 30-50percent alkali / 0.33 h / 45 - 50 °C 2: 5 h / 165 - 185 °C View Scheme
参考文献
Konstantinchenko, A. A.; Morkovnik, A. S.; Pozharskii, A. F.; Tertov, B. A.
Chemistry of Heterocyclic Compounds (New York, NY, United States), 1985 , vol. 21, # 12 p. 1398 - 1399
Khimiya Geterotsiklicheskikh Soedinenii, 1985 , vol. 21, # 12 p. 1694 - 1695
反应条件
T=165 - 185°C; 5 h; Yield given. Yields of byproduct given;
参考文献
Konstantinchenko, A. A.; Morkovnik, A. S.; Pozharskii, A. F.; Tertov, B. A.
Chemistry of Heterocyclic Compounds (New York, NY, United States), 1985 , vol. 21, # 12 p. 1398 - 1399
Khimiya Geterotsiklicheskikh Soedinenii, 1985 , vol. 21, # 12 p. 1694 - 1695
反应条件
potassium hydroxide 5 h; Heatingother temperature; Product distribution;
参考文献
Konstantinchenko, A. A.; Morkovnik, A. S.; Pozharskii, A. F.; Tertov, B. A.
Chemistry of Heterocyclic Compounds (New York, NY, United States), 1985 , vol. 21, # 12 p. 1398 - 1399
Khimiya Geterotsiklicheskikh Soedinenii, 1985 , vol. 21, # 12 p. 1694 - 1695
反应条件
acetic acid in acetonitrile Mannich reaction; 6 h; Heating;
参考文献
Gu, Huan; Guo, Yuan; Shi, Zhen
Synthetic Communications, 2006 , vol. 36, # 22 p. 3335 - 3338
反应条件
acetic acid in acetonitrile Mannich reaction; 6 h; Heating;
参考文献
Gu, Huan; Guo, Yuan; Shi, Zhen
Synthetic Communications, 2006 , vol. 36, # 22 p. 3335 - 3338
