1,3-二氢-1,1-二甲基-2,1-苯并氧硅杂环戊二烯合成路线 （共 95 条）
反应条件
1: tetrahydrofuran; diethyl ether / 4 h / -78 - 20 °C 2: biphenyl-2-yl-di-tert-butyl-phosphane; lithium tert-butylate; [(Mes)Cu]n / 1,4-dioxane / 4 h / 20 °C View Scheme
参考文献
Miki, Yuya; Hirano, Koji; Satoh, Tetsuya; Miura, Masahiro
Organic Letters, 2013 , vol. 15, # 1 p. 172 - 175
参考文献
Marcuccio, Sebastian M.; Epa, Ruwan; Moslmani, Maisa; Hughes, Andrew B.
Tetrahedron Letters, 2011 , vol. 52, # 52 p. 7178 - 7181
反应条件
in tetrahydrofuran; diethyl ether T=0 - 20°C;
参考文献
Chen, Jinshui; Tanaka, Masaaki; Sahoo, Akhila K.; Takeda, Masahide; Yada, Akira; Nakao, Yoshiaki; Hiyama, Tamejiro
Bulletin of the Chemical Society of Japan, 2010 , vol. 83, # 5 p. 554 - 569
反应条件
in tetrahydrofuran; diethyl ether T=-78 - 20°C;
参考文献
Wang, Zhen; Chang, Sukbok
Organic Letters, 2013 , vol. 15, # 8 p. 1990 - 1993
反应条件
in tetrahydrofuran; diethyl ether T=-78 - 20°C;
参考文献
Wang, Zhen; Chang, Sukbok
Organic Letters, 2013 , vol. 15, # 8 p. 1990 - 1993
反应条件
potassium carbonate; trifuran-2-yl-phosphane; palladium dichloride in dimethyl sulfoxide
T=35°C; 21 h;
参考文献
Nakao, Yoshiaki; Hiyama, Tamejiro
Patent: US2009/69577 A1, 2009 ;
Location in patent: Page/Page column 20 ;
反应条件
potassium carbonate; copper(l) iodide; bis(η3-allyl-μ-chloropalladium(II)); dicyclohexyl(2',6'-diisopropoxy-[1,1'-biphenyl]-2-yl)phosphine in tetrahydrofuran; N,N-dimethyl-formamide
T=75°C; 27 h; Product distribution / selectivity;
参考文献
Nakao, Yoshiaki; Hiyama, Tamejiro
Patent: US2009/69577 A1, 2009 ;
Location in patent: Page/Page column 21; 24 ;
反应条件
potassium carbonate; copper(l) iodide; bis(η3-allyl-μ-chloropalladium(II)); dicyclohexyl(2',6'-diisopropoxy-[1,1'-biphenyl]-2-yl)phosphine in tetrahydrofuran; N,N-dimethyl-formamide
T=75°C; 26 h; Product distribution / selectivity;
参考文献
Nakao, Yoshiaki; Hiyama, Tamejiro
Patent: US2009/69577 A1, 2009 ;
Location in patent: Page/Page column 21; 24 ;
反应条件
potassium carbonate; copper(l) iodide; bis(η3-allyl-μ-chloropalladium(II)); dicyclohexyl(2',6'-diisopropoxy-[1,1'-biphenyl]-2-yl)phosphine in tetrahydrofuran; N,N-dimethyl-formamide
T=75°C; 25 h; Product distribution / selectivity;
参考文献
Nakao, Yoshiaki; Hiyama, Tamejiro
Patent: US2009/69577 A1, 2009 ;
Location in patent: Page/Page column 21; 23-24 ;
反应条件
potassium carbonate; copper(l) iodide; bis(η3-allyl-μ-chloropalladium(II)); dicyclohexyl(2',6'-diisopropoxy-[1,1'-biphenyl]-2-yl)phosphine in tetrahydrofuran; N,N-dimethyl-formamide
T=75°C; 25 h; Product distribution / selectivity;
参考文献
Nakao, Yoshiaki; Hiyama, Tamejiro
Patent: US2009/69577 A1, 2009 ;
Location in patent: Page/Page column 21-22; 24 ;
