1,3-二氢-1,1-二甲基-2,1-苯并氧硅杂环戊二烯合成路线 （共 95 条）
反应条件
1: thien-2-yl bromide With magnesium
2: 1,1-dimethyl-1,3-dihydrobenzo[c][1,2]oxasilole in tetrahydrofuran
T=0 - 20°C; 22 h;
3: With water; ammonium chloride in tetrahydrofuran; diethyl ether
参考文献
Nakao, Yoshiaki; Hiyama, Tamejiro
Patent: US2009/69577 A1, 2009 ;
Location in patent: Page/Page column 15-16 ;
反应条件
in tetrahydrofuran
T=20°C; 22 h;
参考文献
Nakao, Yoshiaki; Imanaka, Hidekazu; Sahoo, Akhila K.; Yada, Akira; Hiyama, Tamejiro
Journal of the American Chemical Society, 2005 , vol. 127, # 19 p. 6952 - 6953
反应条件
in tetrahydrofuran
T=0 - 20°C;
参考文献
Nakao, Yoshiaki; Chen, Jinshui; Imanaka, Hidekazu; Hiyama, Tamejiro; Ichikawa, Yoshitaka; Duan, Wei-Liang; Shintani, Ryo; Hayashi, Tamio
Journal of the American Chemical Society, 2007 , vol. 129, # 29 p. 9137 - 9143
参考文献
Marcuccio, Sebastian M.; Epa, Ruwan; Moslmani, Maisa; Hughes, Andrew B.
Tetrahedron Letters, 2011 , vol. 52, # 52 p. 7178 - 7181
反应条件
1: 95 percent / tetrahydrofuran; diethyl ether / -78 - 20 °C
2: 94 percent / K2CO3; N-(2-diphenylphosphinobenzylidene)cyclohexylamine; PdCl2 / dimethylsulfoxide; H2O / 13 h / 50 °C
View Scheme
参考文献
Nakao, Yoshiaki; Imanaka, Hidekazu; Sahoo, Akhila K.; Yada, Akira; Hiyama, Tamejiro
Journal of the American Chemical Society, 2005 , vol. 127, # 19 p. 6952 - 6953
