1,3-二氢-1,1-二甲基-2,1-苯并氧硅杂环戊二烯合成路线 （共 95 条）
反应条件
bis(1,2-diphenylphosphino)benzene; [Rd(OH)(cod)]2 in toluene
T=100°C; 0.5 h;
参考文献
Nakao, Yoshiaki; Takeda, Masahide; Chen, Jinshui; Hiyama, Tamejiro
Synlett, 2008 , # 5 p. 774 - 776
反应条件
bis(1,2-diphenylphosphino)benzene; [Rd(OH)(cod)]2 in toluene
T=100°C; 0.5 h;
参考文献
Nakao, Yoshiaki; Takeda, Masahide; Chen, Jinshui; Hiyama, Tamejiro
Synlett, 2008 , # 5 p. 774 - 776
反应条件
1.1: conc. hydrochloric acid / 20 °C
2.1: n-BuLi / tetrahydrofuran; hexane / 0.67 h / -78 °C
2.2: 83 percent / tetrahydrofuran; hexane / -78 - 20 °C
3.1: 83 percent / p-toluenesulfonic acid monohydrate / methanol / 16 h / 20 °C
View Scheme
参考文献
Nakao, Yoshiaki; Imanaka, Hidekazu; Chen, Jinshui; Yada, Akira; Hiyama, Tamejiro
Journal of Organometallic Chemistry, 2007 , vol. 692, # 1-3 p. 585 - 603
反应条件
bis(1,2-diphenylphosphino)benzene; [Rd(OH)(cod)]2 in toluene
T=100°C; 1 h;
参考文献
Nakao, Yoshiaki; Takeda, Masahide; Chen, Jinshui; Hiyama, Tamejiro
Synlett, 2008 , # 5 p. 774 - 776
反应条件
bis(1,2-diphenylphosphino)benzene; [Rd(OH)(cod)]2 in toluene
T=100°C; 3 h;
参考文献
Nakao, Yoshiaki; Takeda, Masahide; Chen, Jinshui; Hiyama, Tamejiro
Synlett, 2008 , # 5 p. 774 - 776
反应条件
bis(1,2-diphenylphosphino)benzene; [Rd(OH)(cod)]2 in toluene
T=100°C; 3 h;
参考文献
Nakao, Yoshiaki; Takeda, Masahide; Chen, Jinshui; Hiyama, Tamejiro
Synlett, 2008 , # 5 p. 774 - 776
反应条件
bis(1,2-diphenylphosphino)benzene; [Rd(OH)(cod)]2 in toluene
T=100°C; 102 h;
参考文献
Nakao, Yoshiaki; Takeda, Masahide; Chen, Jinshui; Hiyama, Tamejiro
Synlett, 2008 , # 5 p. 774 - 776
反应条件
1.1: n-BuLi / tetrahydrofuran; hexane / 0.67 h / -78 °C
1.2: 83 percent / tetrahydrofuran; hexane / -78 - 20 °C
2.1: 83 percent / p-toluenesulfonic acid monohydrate / methanol / 16 h / 20 °C
View Scheme
参考文献
Nakao, Yoshiaki; Imanaka, Hidekazu; Chen, Jinshui; Yada, Akira; Hiyama, Tamejiro
Journal of Organometallic Chemistry, 2007 , vol. 692, # 1-3 p. 585 - 603
反应条件
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; water; potassium carbonate in dimethyl sulfoxide
T=110°C; Hiyama coupling;
参考文献
Shirbin, Steven J.; Boughton, Berin A.; Zammit, Steven C.; Zanatta, Shannon D.; Marcuccio, Sebastian M.; Hutton, Craig A.; Williams, Spencer J.
Tetrahedron Letters, 2010 , vol. 51, # 22 p. 2971 - 2974
反应条件
tris(dibenzylideneacetone)dipalladium (0) in tetrahydrofuran
T=50°C; 3 h;
参考文献
Nakao, Yoshiaki; Ebata, Shiro; Chen, Jinshui; Imanaka, Hidekazu; Hiyama, Tamejiro
Chemistry Letters, 2007 , vol. 36, # 5 p. 606 - 607
