1,3-二氢-1,1-二甲基-2,1-苯并氧硅杂环戊二烯合成路线 （共 95 条）
反应条件
copper(l) iodide; bis(η3-allyl-μ-chloropalladium(II)); potassium carbonate; dicyclohexyl(2',6'-diisopropoxy-[1,1'-biphenyl]-2-yl)phosphine in tetrahydrofuran; N,N-dimethyl-formamide
T=75°C; 7 h; Inert atmosphere;
参考文献
Chen, Jinshui; Tanaka, Masaaki; Sahoo, Akhila K.; Takeda, Masahide; Yada, Akira; Nakao, Yoshiaki; Hiyama, Tamejiro
Bulletin of the Chemical Society of Japan, 2010 , vol. 83, # 5 p. 554 - 569
反应条件
copper(l) iodide; bis(η3-allyl-μ-chloropalladium(II)); potassium carbonate; dicyclohexyl(2',6'-diisopropoxy-[1,1'-biphenyl]-2-yl)phosphine in tetrahydrofuran; N,N-dimethyl-formamide
T=75°C; 22 h; Inert atmosphere;
参考文献
Chen, Jinshui; Tanaka, Masaaki; Sahoo, Akhila K.; Takeda, Masahide; Yada, Akira; Nakao, Yoshiaki; Hiyama, Tamejiro
Bulletin of the Chemical Society of Japan, 2010 , vol. 83, # 5 p. 554 - 569
反应条件
copper(l) iodide; bis(η3-allyl-μ-chloropalladium(II)); potassium carbonate; dicyclohexyl(2',6'-diisopropoxy-[1,1'-biphenyl]-2-yl)phosphine in tetrahydrofuran; N,N-dimethyl-formamide
T=75°C; 26 h; Inert atmosphere;
参考文献
Chen, Jinshui; Tanaka, Masaaki; Sahoo, Akhila K.; Takeda, Masahide; Yada, Akira; Nakao, Yoshiaki; Hiyama, Tamejiro
Bulletin of the Chemical Society of Japan, 2010 , vol. 83, # 5 p. 554 - 569
反应条件
1: [2-(hydroxymethyl)phenyl]dimethyl(phenyl)silane With n-butyllithium in tetrahydrofuran; hexane
T=0°C; 0.0833333 h; Inert atmosphere;
2: 4-bromophenylboronic acid pinacol ester With copper(l) iodide; bis(η3-allyl-μ-chloropalladium(II)); dicyclohexyl(2',6'-diisopropoxy-[1,1'-biphenyl]-2-yl)phosphine in tetrahydrofuran; hexane; N,N-dimethyl-formamide
T=75°C; 11 h; Inert atmosphere;
参考文献
Chen, Jinshui; Tanaka, Masaaki; Sahoo, Akhila K.; Takeda, Masahide; Yada, Akira; Nakao, Yoshiaki; Hiyama, Tamejiro
Bulletin of the Chemical Society of Japan, 2010 , vol. 83, # 5 p. 554 - 569
反应条件
copper(l) iodide; bis(η3-allyl-μ-chloropalladium(II)); potassium carbonate; dicyclohexyl(2',6'-diisopropoxy-[1,1'-biphenyl]-2-yl)phosphine in tetrahydrofuran; N,N-dimethyl-formamide
T=75°C; 8 h; Inert atmosphere;
参考文献
Chen, Jinshui; Tanaka, Masaaki; Sahoo, Akhila K.; Takeda, Masahide; Yada, Akira; Nakao, Yoshiaki; Hiyama, Tamejiro
Bulletin of the Chemical Society of Japan, 2010 , vol. 83, # 5 p. 554 - 569
反应条件
copper(l) iodide; bis(η3-allyl-μ-chloropalladium(II)); potassium carbonate; dicyclohexyl(2',6'-diisopropoxy-[1,1'-biphenyl]-2-yl)phosphine in tetrahydrofuran; N,N-dimethyl-formamide
T=75°C; 7 h; Inert atmosphere;
参考文献
Chen, Jinshui; Tanaka, Masaaki; Sahoo, Akhila K.; Takeda, Masahide; Yada, Akira; Nakao, Yoshiaki; Hiyama, Tamejiro
Bulletin of the Chemical Society of Japan, 2010 , vol. 83, # 5 p. 554 - 569
反应条件
copper(l) iodide; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II) dichloromethane adduct; potassium carbonate in tetrahydrofuran; N,N-dimethyl-formamide
T=50°C; 8 h; Inert atmosphere;
参考文献
Chen, Jinshui; Tanaka, Masaaki; Sahoo, Akhila K.; Takeda, Masahide; Yada, Akira; Nakao, Yoshiaki; Hiyama, Tamejiro
Bulletin of the Chemical Society of Japan, 2010 , vol. 83, # 5 p. 554 - 569
反应条件
copper(l) iodide; bis(η3-allyl-μ-chloropalladium(II)); potassium carbonate; dicyclohexyl(2',6'-diisopropoxy-[1,1'-biphenyl]-2-yl)phosphine in tetrahydrofuran; N,N-dimethyl-formamide
T=50°C; 6 h; Inert atmosphere;
参考文献
Chen, Jinshui; Tanaka, Masaaki; Sahoo, Akhila K.; Takeda, Masahide; Yada, Akira; Nakao, Yoshiaki; Hiyama, Tamejiro
Bulletin of the Chemical Society of Japan, 2010 , vol. 83, # 5 p. 554 - 569
反应条件
copper(l) iodide; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II) dichloromethane adduct; potassium carbonate in tetrahydrofuran; N,N-dimethyl-formamide
T=50°C; 9 h; Inert atmosphere;
参考文献
Chen, Jinshui; Tanaka, Masaaki; Sahoo, Akhila K.; Takeda, Masahide; Yada, Akira; Nakao, Yoshiaki; Hiyama, Tamejiro
Bulletin of the Chemical Society of Japan, 2010 , vol. 83, # 5 p. 554 - 569
反应条件
copper(l) iodide; bis(η3-allyl-μ-chloropalladium(II)); potassium carbonate; dicyclohexyl(2',6'-diisopropoxy-[1,1'-biphenyl]-2-yl)phosphine in tetrahydrofuran; N,N-dimethyl-formamide
T=75°C; 24 h; Inert atmosphere;
参考文献
Chen, Jinshui; Tanaka, Masaaki; Sahoo, Akhila K.; Takeda, Masahide; Yada, Akira; Nakao, Yoshiaki; Hiyama, Tamejiro
Bulletin of the Chemical Society of Japan, 2010 , vol. 83, # 5 p. 554 - 569
