1,3-二氢-1,1-二甲基-2,1-苯并氧硅杂环戊二烯合成路线 （共 95 条）
反应条件
copper(l) iodide; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II) dichloromethane adduct; potassium carbonate in tetrahydrofuran; N,N-dimethyl-formamide
T=50°C; 6 h; Inert atmosphere;
参考文献
Chen, Jinshui; Tanaka, Masaaki; Sahoo, Akhila K.; Takeda, Masahide; Yada, Akira; Nakao, Yoshiaki; Hiyama, Tamejiro
Bulletin of the Chemical Society of Japan, 2010 , vol. 83, # 5 p. 554 - 569
反应条件
copper(l) iodide; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II) dichloromethane adduct; potassium carbonate in tetrahydrofuran; N,N-dimethyl-formamide
T=50°C; 6 h; Inert atmosphere;
参考文献
Chen, Jinshui; Tanaka, Masaaki; Sahoo, Akhila K.; Takeda, Masahide; Yada, Akira; Nakao, Yoshiaki; Hiyama, Tamejiro
Bulletin of the Chemical Society of Japan, 2010 , vol. 83, # 5 p. 554 - 569
反应条件
copper(l) iodide; bis(η3-allyl-μ-chloropalladium(II)); potassium carbonate; dicyclohexyl(2',6'-diisopropoxy-[1,1'-biphenyl]-2-yl)phosphine in tetrahydrofuran; N,N-dimethyl-formamide
T=75°C; 22 h; Inert atmosphere;
参考文献
Chen, Jinshui; Tanaka, Masaaki; Sahoo, Akhila K.; Takeda, Masahide; Yada, Akira; Nakao, Yoshiaki; Hiyama, Tamejiro
Bulletin of the Chemical Society of Japan, 2010 , vol. 83, # 5 p. 554 - 569
反应条件
1,1'-bis-(diphenylphosphino)ferrocene; [NiCl2(1,2-dimethoxyethane)]; caesium carbonate; zinc; tri-cyclo-hexyl-phosphine in ethylene glycol dimethyl ether; N,N-dimethyl-formamide
T=20 - 80°C; Suzuki-Miyaura cross-coupling reaction; 30 h; Inert atmosphere; chemoselective reaction;
参考文献
Tang, Shi; Takeda, Masahide; Nakao, Yoshiaki; Hiyama, Tamejiro
Chemical Communications, 2011 , vol. 47, # 1 p. 307 - 309
反应条件
bis(1,2-diphenylphosphino)benzene; [Rd(OH)(cod)]2 in toluene
T=100°C; 20 h;
参考文献
Nakao, Yoshiaki; Takeda, Masahide; Chen, Jinshui; Hiyama, Tamejiro
Synlett, 2008 , # 5 p. 774 - 776
反应条件
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; water; potassium carbonate in dimethyl sulfoxide
T=110°C; Hiyama coupling;
参考文献
Shirbin, Steven J.; Boughton, Berin A.; Zammit, Steven C.; Zanatta, Shannon D.; Marcuccio, Sebastian M.; Hutton, Craig A.; Williams, Spencer J.
Tetrahedron Letters, 2010 , vol. 51, # 22 p. 2971 - 2974
反应条件
1: o-pentamethyldisilylbenzyl alcohol With n-butyllithium in diethyl ether; hexane
0.5 h;
2: in tetrahydrofuran; diethyl ether; hexane
T=0°C; 0.333333 h;
3: cyclohexenon in tetrahydrofuran; diethyl ether; hexane
T=20°C; 13 h;
参考文献
Hudrlik, Paul F.; Arango, Jose O.; Hijji, Yousef M.; Okoro, Cosmas O.; Hudrlik, Anne M.
Canadian Journal of Chemistry, 2000 , vol. 78, # 11 p. 1421 - 1427
反应条件
bis(1,2-diphenylphosphino)benzene; [Rd(OH)(cod)]2 in toluene
T=100°C; 17 h;
参考文献
Nakao, Yoshiaki; Takeda, Masahide; Chen, Jinshui; Hiyama, Tamejiro
Synlett, 2008 , # 5 p. 774 - 776
反应条件
bis(1,2-diphenylphosphino)benzene; [Rd(OH)(cod)]2 in toluene
T=100°C; 2 h;
参考文献
Nakao, Yoshiaki; Takeda, Masahide; Chen, Jinshui; Hiyama, Tamejiro
Synlett, 2008 , # 5 p. 774 - 776
反应条件
1: o-pentamethyldisilylbenzyl alcohol With potassium hydride in tetrahydrofuran
T=0°C;
2: benzaldehyde in tetrahydrofuran
T=20°C; 1 h;
参考文献
Hudrlik, Paul F.; Arango, Jose O.; Hijji, Yousef M.; Okoro, Cosmas O.; Hudrlik, Anne M.
Canadian Journal of Chemistry, 2000 , vol. 78, # 11 p. 1421 - 1427
