2-甲基-3-戊基环氧乙烷合成路线 (共 32 条)
参考文献
Daicel Chemical Industries, Ltd.
Patent: US6229023 B1, 2001 ;
参考文献
Yissum Research Development Company of Hebrew University of Jerusalem; Yeda Research and Development Company Ltd.
Patent: US6573394 B1, 2003 ;
反应条件
[Fe(CF3SO3)2(1-[2′-(6'-methylpyridyl)methyl]-4,7-dimethyl-1,4,7-triazacyclononane)]; water; dihydrogen peroxide in acetonitrile T=0°C; 0.5 h; Green chemistry; chemoselective reaction;
参考文献
Sakata, Yasuyuki; Katayama, Yuji; Ishii, Yasutaka
Chemistry Letters, 1992 , # 4 p. 671 - 674
反应条件
2-hydroxy-1,3-isoindolinedione; hexacarbonyl molybdenum; oxygen; anhydrous cobalt diacetate in benzonitrile T=60°C; Epoxidation; Oxidation; 12 h; Product distribution; Further Variations:Reaction partnersTemperatures;
参考文献
Iwahama, Takahiro; Hatta, Gou; Sakaguchi, Satoshi; Ishii, Yasutaka
Chemical Communications, 2000 , # 2 p. 163 - 164
反应条件
3-chloro-benzenecarboperoxoic acid in tetrahydrofuran T=66°C; 0.05 h; other solvents, temperature, time; Product distribution;
参考文献
Macdonald, Timothy L.; Narasimhan, N.; Burka, Leo T.
Journal of the American Chemical Society, 1980 , vol. 102, # 26 p. 7760 - 7765
反应条件
peroxytungstophosphate; sulfuric acid; dihydrogen peroxide in chloroform 24 h; Heating; Yield given. Yields of byproduct given;
参考文献
Sakata, Yasuyuki; Katayama, Yuji; Ishii, Yasutaka
Chemistry Letters, 1992 , # 4 p. 671 - 674
反应条件
sec-phenethyl alcohol; oxygen; 2-hydroxy-1,3-isoindolinedione; 1,1,1,3,3,3-hexafluoro-2-propanone in benzonitrile T=80°C; Oxidation; 24 h; Product distribution; Further Variations:SolventsReagentsCatalystsTemperatures;
参考文献
Iwahama, Takahiro; Sakaguchi, Satoshi; Ishii, Yasutaka
Heterocycles, 2000 , vol. 52, # 2 p. 693 - 705
反应条件
ruthenium(IV) oxide; benzene-1,2,4,5-tetracarboxylic acid; oxygen; acetaldehyde in acetone T=40°C; 3 h; var. internal and methyl-substituted alkenes; Product distributionMechanism;
参考文献
Kaneda, Kiyotomi; Haruna, Shigeru; Imanaka, Toshinobu; Kawamoto, Keiji
Journal of the Chemical Society, Chemical Communications, 1990 , # 21 p. 1467 - 1468
反应条件
potassium hydroxide; sodium hydroxide
参考文献
Detoeuf
Bulletin de la Societe Chimique de France, 1922 , vol. <4> 31, p. 178
参考文献
Kirrmann; Chancel
Bulletin de la Societe Chimique de France, 1951 , p. 227