[2,2’]-双噻吩-5,5‘-二甲醛合成路线 （共 31 条）
反应条件
[2,2']bipyridinyl; nickel diacetate; sodium tert-pentoxide in tetrahydrofuran T=45°C; 0.00472222 h;
参考文献
Forst, Yves; Becker, Sandrine; Caubere, Paul
Tetrahedron, 1994 , vol. 50, # 41 p. 11893 - 11902
反应条件
PdCl(C3H5)(dppb); potassium acetate in N,N-dimethyl acetamide T=120°C; 20 h; Inert atmosphere; regioselective reaction;
参考文献
Derridj, Fazia; Gottumukkala, Aditya L.; Djebbar, Safia; Doucet, Henri
European Journal of Inorganic Chemistry, 2008 , # 16 p. 2550 - 2559
反应条件
1: [13C]-Caffeine With pyridine; palladium diacetate; copper (II) acetate monohydrate in 1,4-dioxane T=20°C; 0.166667 h; Inert atmosphere; 2: thiophene-2-carbaldehyde in 1,4-dioxane T=120°C; 20 h; Inert atmosphere;
参考文献
Xi, Peihua; Yang, Fan; Qin, Song; Zhao, Dongbing; Lan, Jingbo; Gao, Ge; Hu, Changwei; You, Jingsong
Journal of the American Chemical Society, 2010 , vol. 132, # 6 p. 1822 - 1824
反应条件
tetrakis(triphenylphosphine) palladium(0); sodium carbonate in tetrahydrofuran; water Suzuki Coupling; 24 h; Inert atmosphereReflux;
参考文献
Khanasa, Tanika; Jantasing, Nittaya; Morada, Somphob; Leesakul, Nararak; Tarsang, Ruangchai; Namuangruk, Supawadee; Kaewin, Tinnagon; Jungsuttiwong, Siriporn; Sudyoadsuk, Taweesak; Promarak, Vinich
European Journal of Organic Chemistry, 2013 , # 13 p. 2608 - 2620
反应条件
1: C9H11BrMgO With bismuth(III) chloride 2: 5-Bromothiophene-2-carboxaldehyde With potassium phosphate; palladium diacetate; triphenylphosphine in N,N-dimethyl-formamide T=90°C; 1 h; Inert atmosphere; chemoselective reaction;
参考文献
Rao, Maddali L. N.; Banerjee, Debasis; Dhanorkar, Ritesh J.
Synlett, 2011 , # 9 p. 1324 - 1330
反应条件
1: 4-methoxyphenyl magnesium bromide With bismuth(III) chloride 2: 5-Bromothiophene-2-carboxaldehyde With potassium phosphate; palladium diacetate; triphenylphosphine in N,N-dimethyl-formamide T=90°C; 1 h; Inert atmosphere;
参考文献
Rao, Maddali L. N.; Banerjee, Debasis; Dhanorkar, Ritesh J.
Synlett, 2011 , # 9 p. 1324 - 1330
反应条件
1: (4-fluoro-phenyl)-magnesium bromide With bismuth(III) chloride 2: 5-Bromothiophene-2-carboxaldehyde With potassium phosphate; palladium diacetate; triphenylphosphine in N,N-dimethyl-formamide T=90°C; 1 h; Inert atmosphere; chemoselective reaction;
参考文献
Rao, Maddali L. N.; Banerjee, Debasis; Dhanorkar, Ritesh J.
Synlett, 2011 , # 9 p. 1324 - 1330
反应条件
1: C10H13BrMgO With bismuth(III) chloride 2: 5-Bromothiophene-2-carboxaldehyde With potassium phosphate; palladium diacetate; triphenylphosphine in N,N-dimethyl-formamide T=90°C; 1 h; Inert atmosphere; chemoselective reaction;
参考文献
Rao, Maddali L. N.; Banerjee, Debasis; Dhanorkar, Ritesh J.
Synlett, 2011 , # 9 p. 1324 - 1330
反应条件
1: thien-2-ylmagnesium bromide With bismuth(III) chloride 2: 5-Bromothiophene-2-carboxaldehyde With potassium phosphate; palladium diacetate; triphenylphosphine in N,N-dimethyl-formamide T=90°C; 1 h; Inert atmosphere;
参考文献
Rao, Maddali L. N.; Banerjee, Debasis; Dhanorkar, Ritesh J.
Synlett, 2011 , # 9 p. 1324 - 1330
反应条件
1: 1-methyl-1H-imidazole With pyridine; palladium diacetate; copper (II) acetate monohydrate in 1,4-dioxane T=20°C; 0.166667 h; Inert atmosphere; 2: thiophene-2-carbaldehyde in 1,4-dioxane T=120°C; 20 h; Inert atmosphere;
参考文献
Xi, Peihua; Yang, Fan; Qin, Song; Zhao, Dongbing; Lan, Jingbo; Gao, Ge; Hu, Changwei; You, Jingsong
Journal of the American Chemical Society, 2010 , vol. 132, # 6 p. 1822 - 1824
