(8R)-8-乙酰基-7,8,9,10-四氢-6,8,11-三羟基-1-甲氧基-5,12-并四苯醌合成路线 （共 36 条）
参考文献
Kleyer, Don L.; Koch, Tad H.
Journal of the American Chemical Society, 1983 , vol. 105, # 8 p. 2504 - 2505
反应条件
boron trichloride in dichloromethane T=-78°C; Yield given;
参考文献
Russella; Kraussa; Warrener; Irvine
Tetrahedron Letters, 1984 , vol. 25, # 14 p. 1517 - 1520
反应条件
2,2'-azo-bisisobutyronitrile; tri-n-butyl-tin hydride in benzene T=80°C; temp.: > 80 deg C;
参考文献
Horton; Priebe; Sznaidman
Carbohydrate research, 1989 , vol. 187, # 1 p. 149 - 153
反应条件
tris(hydroxymethyl)methylamine hydrochloride; tri-(hydroxymethyl)-methylamine in methanol
参考文献
Kleyer, Don L.; Koch, Tad H.
Journal of the American Chemical Society, 1984 , vol. 106, # 8 p. 2380 - 2387
反应条件
hydrogen; palladium on activated charcoal in ethanol 3 h; other reducing agent: sodium dithionite; other catalyst: Pd on barium sulfate; Yield given. Yields of byproduct given;
参考文献
Sallam; Whistler; Cassady
Canadian Journal of Chemistry, 1985 , vol. 63, # 10 p. 2697 - 2702
反应条件
Tris buffer in water T=25°C; Rate constantProduct distribution;
参考文献
Bird; Gaudiano; Koch
Journal of the American Chemical Society, 1991 , vol. 113, # 1 p. 308 - 315
反应条件
oxygen in water T=0°C; Mechanism;
参考文献
Gaudiano, Giorgio; Koch, Tad H.
Journal of the American Chemical Society, 1990 , vol. 112, # 25 p. 9423 - 9425
反应条件
sulfuric acid; trifluoroacetic acid; mercury(II) oxide 1.) THF, reflux; 2.) 50 deg C; Yield given. Multistep reaction;
参考文献
Fujioka; Yamamoto; Annoura; Miyazaki; Kita
Chemical and Pharmaceutical Bulletin, 1990 , vol. 38, # 7 p. 1872 - 1876
反应条件
1: CsF / dimethylformamide / Ambient temperature 2: BCl3 / CH2Cl2 / -78 °C View Scheme
参考文献
Russella; Kraussa; Warrener; Irvine
Tetrahedron Letters, 1984 , vol. 25, # 14 p. 1517 - 1520
反应条件
1: various solvent(s) / 17 h 2: 0.01 N sodium methoxide / tetrahydrofuran / 5 h / 20 °C / other reagent: potassium carbonate View Scheme
参考文献
Sallam; Whistler; Cassady
Canadian Journal of Chemistry, 1985 , vol. 63, # 10 p. 2697 - 2702
