1-苯基-4-戊烯-1-酮合成路线 （共 116 条）
反应条件
2,2'-azo-bisisobutyronitrile in benzene
T=61°C; 53 h; Product distributionMechanism;
参考文献
Li, Xianfeng; Chen, Jian J.; Tanner, Dennis D.
Journal of Organic Chemistry, 1996 , vol. 61, # 13 p. 4314 - 4318
反应条件
2,2'-azo-bisisobutyronitrile in benzene
T=61°C; 53 h; Product distributionMechanism;
参考文献
Li, Xianfeng; Chen, Jian J.; Tanner, Dennis D.
Journal of Organic Chemistry, 1996 , vol. 61, # 13 p. 4314 - 4318
反应条件
2,2'-azo-bisisobutyronitrile in benzene
T=61°C; 48 h;
参考文献
Li, Xianfeng; Chen, Jian J.; Tanner, Dennis D.
Journal of Organic Chemistry, 1996 , vol. 61, # 13 p. 4314 - 4318
反应条件
1: CH2Cl2 / -78 °C
2: 63 percent / CH2Cl2 / 0.17 h / Ambient temperature
View Scheme
参考文献
Zhdankin, Viktor V.; Mullikin, Michelle; Tykwinski, Rik; Berglund, Bruce; Caple, Ronald; et al.
Journal of Organic Chemistry, 1989 , vol. 54, # 11 p. 2605 - 2608
反应条件
1: 89 percent
2: 75 percent / silica gel
View Scheme
参考文献
Ng, Kai S.; Alper, Howard
Journal of Organic Chemistry, 1981 , vol. 46, # 5 p. 1039 - 1041
反应条件
1: 2.) n-BuLi / 1.) THF, 30 min, room temperature, 2.) THF, 60 min, -78 deg C
View Scheme
参考文献
Ng, Kai S.; Alper, Howard
Journal of Organic Chemistry, 1981 , vol. 46, # 5 p. 1039 - 1041
反应条件
1: 81 percent / tetrahydrofuran; diethyl ether; hexane / -78 deg C -> r.t.
2: 36 percent / diethyl ether / 3 h / -30 °C / also in THF, at -50 deg C
View Scheme
参考文献
Thomas, Edward W.; Szmuszkovicz, Jaqueline R.
Journal of Organic Chemistry, 1990 , vol. 55, # 24 p. 6054 - 6058
反应条件
2,2'-azo-bisisobutyronitrile in benzene
T=61°C; 53 h; Product distributionMechanism;
参考文献
Li, Xianfeng; Chen, Jian J.; Tanner, Dennis D.
Journal of Organic Chemistry, 1996 , vol. 61, # 13 p. 4314 - 4318
反应条件
trimethylsilyl trifluoromethanesulfonate; iodosylbenzene in dichloromethane
Ambient temperaturevar. trimethylsilyl ketene acetals of esters/lactones;
参考文献
Moriarty, Robert M.; Epa, Widanagamage R.; Prakash, Om
Journal of Chemical Research - Part S, 1997 , # 7 p. 262 - 263
反应条件
1: 1.) LiCuBr2 / 1.) 1 h, -20 deg C, THF, 2.) 3 h, -20 deg C, THF
2: 3.0 N HCl / 0.5 h / 25 °C
View Scheme
参考文献
Wijkens, P.; Vermeer, P.
Journal of Organometallic Chemistry, 1986 , vol. 301, p. 247 - 256
