3-甲氧基苯硼酸频哪醇酯合成路线 （共 27 条）
反应条件
1: tBuCH2CH2B(H)NiPr2; 3-methoxy benzene diazonium tetrafluoroborate With biscyclopentadienyliron(II) in acetonitrile T=20°C; 2.5 h; 2: With methanol in acetonitrile T=0 - 20°C; 1 h; 3: 2,3-dimethylbutane-2,3-diol in diethyl ether; acetonitrile T=20°C; 4 h; Reagent/catalyst;
参考文献
WO2014/9169 A1, ;
Page/Page column 55 ;
反应条件
in toluene 2.5 h; Inert atmosphereReflux;
参考文献
Tetrahedron Letters, , vol. 53, # 46 p. 6182 - 6185,4
反应条件
bis(η4-1,5-cyclooctadiene)-di-μ-methoxy-diiridium(I); 4,4'-di-tert-butyl-2,2'-dipyridyl in tetrahydrofuran T=25°C; 24 h; Title compound not separated from byproducts;
参考文献
Journal of the American Chemical Society, , vol. 127, # 30 p. 10539 - 10544
反应条件
Ni(PCy3)2Cl2; 1,1,3,3-tetramethyldisiloxane; K3PO4 in toluene T=120°C; 15 h; Inert atmosphere;
参考文献
Organic Letters, , vol. 14, # 11 p. 2918 - 2921
反应条件
copper(l) iodide; sodium hydride in tetrahydrofuran T=20°C;
参考文献
Organic Letters, , vol. 8, # 2 p. 261 - 263
反应条件
C37H51ClFeNPPd; potassium acetate in 1,4-dioxane T=80°C; Suzuki-Miyaura coupling; 3 h; Inert atmosphere;
参考文献
Advanced Synthesis and Catalysis, , vol. 352, # 11-12 p. 2002 - 2010
反应条件
1: 4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl-4',4',5',5'-tetramethyl-1,3,2-dioxaborolane With diethylzinc; sodium t-butanolate in tetrahydrofuran; hexane T=0 - 20°C; 0.5 h; Schlenk techniqueGloveboxInert atmosphere; 2: 3-methoxy-iodobenzene in tetrahydrofuran; hexane T=20 - 75°C; 24 h; Schlenk techniqueGloveboxInert atmosphereSealed tube;
参考文献
Journal of the American Chemical Society, , vol. 135, # 50 p. 18730 - 18733
反应条件
boron trifluoride diethyl etherate in acetonitrile T=0 - 20°C; 0.5 h; Inert atmosphere;
参考文献
Organic Letters, , vol. 14, # 17 p. 4560 - 4563
反应条件
[2,2']bipyridinyl; di-μ-chloro-bis(η4-1,5-cyclooctadiene)diiridium T=80°C; 16 h; Title compound not separated from byproducts.;
参考文献
Journal of the American Chemical Society, , vol. 124, # 3 p. 390 - 391
反应条件
palladium diacetate; triethylamine; bis[2-(diphenylphosphino)phenyl] ether in tetrahydrofuran; 1,4-dioxane T=100°C; 20 h;
参考文献
Organic Letters, , vol. 6, # 24 p. 4419 - 4422
