3-甲氧基苯硼酸频哪醇酯合成路线 （共 27 条）
反应条件
in diethyl ether T=20°C; 4 h; Inert atmosphere;
参考文献
Tetrahedron Letters, , vol. 55, # 10 p. 1702 - 1705
反应条件
1: 4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl-4',4',5',5'-tetramethyl-1,3,2-dioxaborolane With dimethyl zinc; Mg(O-t-Bu)2 in 1,4-dioxane; hexane T=0 - 20°C; 0.5 h; Schlenk techniqueGloveboxInert atmosphere; 2: 2-iodo-3-bromoanisole in 1,4-dioxane; hexane T=20 - 120°C; 24 h; Schlenk techniqueGloveboxInert atmosphere; 3: With water in 1,4-dioxane; hexane T=20°C; 0.0833333 h; Schlenk techniqueGloveboxInert atmosphere; regioselective reaction;
参考文献
Journal of the American Chemical Society, , vol. 135, # 50 p. 18730 - 18733
反应条件
1.1: hydrogenchloride; sodium nitrite / water / 0.5 h / 0 °C 1.2: 0.5 h / 0 - 20 °C 2.1: boron trifluoride diethyl etherate / acetonitrile / 0.5 h / 0 - 20 °C / |Inert atmosphere View Scheme
参考文献
Organic Letters, , vol. 14, # 17 p. 4560 - 4563
反应条件
potassium tetrachloropalladate; potassium acetate T=70°C; Miyaura borylation; 1.5 h; Inert atmosphere;
参考文献
Green Chemistry, , vol. 14, # 3 p. 661 - 667
反应条件
potassium acetate; bis(dibenzylideneacetone)-palladium(0); tri-cyclo-hexyl-phosphine in 1,4-dioxane T=80°C; 48 h;
参考文献
Tetrahedron, , vol. 57, # 49 p. 9813 - 9816
反应条件
1,2-bis(dimethylphosphine)ethane; (η5-indenyl)Ir(cod) T=150°C; 3 h; sealed tube; regioselective reaction;
参考文献
Chemical Communications, , vol. 46, # 41 p. 7724 - 7726
反应条件
1.1: N,N,N',N,-tetramethylethylenediamine; sec.-butyllithium / tetrahydrofuran / 1.25 h / -78 °C / Inert atmosphere 1.2: 1.17 h / -78 °C / Inert atmosphere 2.1: methanol / Inert atmosphere 3.1: Ni(PCy3)2Cl2; K3PO4; 1,1,3,3-tetramethyldisiloxane / toluene / 15 h / 120 °C / Inert atmosphere View Scheme
参考文献
Organic Letters, , vol. 14, # 11 p. 2918 - 2921
反应条件
[Ir(OMe)(1,5-cyclooctadiene)]2 in benzene T=80°C; 12 h; Schlenk techniqueInert atmosphere; Overall yield = 88 percent; regioselective reaction;
参考文献
Journal of the American Chemical Society, , vol. 136, # 10 p. 4003 - 4011
反应条件
iron(III) oxide; di-tert-butyl peroxide; potassium carbonate T=80°C; regioselective reaction;
参考文献
Chemical Communications, , vol. 46, # 18 p. 3170 - 3172
反应条件
[Ir(C8H12)(OCH3)]2; 4,4'-di-tertbutylpyridine in further solvent(s) (N2); heating mixt. of iridium compd., bipyridine deriv., benzene deriv., dodecane and silylborane deriv. at 80°C for 12 h; cooling to room temp., chromy. (silica gel, diethyl ether in hexane (gradient from 0percent to 5percent)), NMR;
参考文献
Organometallics, , vol. 27, # 22 p. 6013 - 6019
