3,5-二甲基苯硼酸频哪醇酯合成路线 （共 42 条）
反应条件
[Ir(C8H12)(OCH3)]2; 4,4'-di-tertbutylpyridine in xylene (N2); heating mixt. of iridium compd., bipyridine deriv., benzene deriv., dodecane and silylborane deriv. at 80°C for 12 h; cooling to room temp., chromy. (silica gel, diethyl ether in hexane (gradient from 0percent to 5percent)), NMR;
参考文献
Organometallics, , vol. 27, # 22 p. 6013 - 6019
反应条件
[Ir(C8H12)(OCH3)]2; 4,4'-di-tertbutylpyridine in N-dodecane; xylene (N2); heating mixt. of iridium compd., bipyridine deriv., benzene deriv., dodecane and silylborane deriv. at 80°C for 12 h; cooling to room temp., chromy. (silica gel, diethyl ether in hexane (gradient from 0percent to 5percent)), NMR;
参考文献
Organometallics, , vol. 27, # 22 p. 6013 - 6019
反应条件
in perdeuterocyclohexane (Schlenk; N2 atm.) to a soln. of complex and diborolane in cyclohexane-d12 was added a soln. of boryl-compound followed by m-xylene, allowed to stabd at room temp.; not sepd., detected by NMR spectra;
参考文献
Journal of the American Chemical Society, , vol. 127, # 41 p. 14263 - 14278
反应条件
in dichloromethane 6 h;
参考文献
Organic Letters, , vol. 12, # 23 p. 5474 - 5477
反应条件
1: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / dimethyl sulfoxide / 2 h / 80 °C / |Inert atmosphere 2: dimethyl sulfoxide / 0.5 h / 20 °C View Scheme
参考文献
Tetrahedron Letters, , vol. 54, # 2 p. 166 - 169
反应条件
C38H70ClIrN4O2P2 T=100°C; 24 h; Inert atmosphere;
参考文献
Angewandte Chemie - International Edition, , vol. 51, # 46 p. 11478 - 11482
Angew. Chem., , vol. 124, # 46 p. 11645 - 11649,5
反应条件
[Ir(μ-Cl)(cyclooctene)2]2; C44H66N4O2Si2 T=100°C; 24 h; Inert atmosphere;
参考文献
Angewandte Chemie - International Edition, , vol. 51, # 46 p. 11478 - 11482
Angew. Chem., , vol. 124, # 46 p. 11645 - 11649,5
反应条件
copper(ll) bromide in methanol T=80°C;
参考文献
Murphy, Jaclyn M.; Liao, Xuebin; Hartwig, John F.
Journal of the American Chemical Society, 2007 , vol. 129, # 50 p. 15434 - 15435
反应条件
copper dichloride in methanol T=90°C;
参考文献
Murphy, Jaclyn M.; Liao, Xuebin; Hartwig, John F.
Journal of the American Chemical Society, 2007 , vol. 129, # 50 p. 15434 - 15435
反应条件
1-fluoro-2,4,6-trimethylpyridinium hexafluorophosphate; C10H18CuN2(1+)*CF3O3S(1-); silver fluoride in tetrahydrofuran T=50°C; 18 h; Inert atmosphere;
参考文献
Fier, Patrick S.; Luo, Jingwei; Hartwig, John F.
Journal of the American Chemical Society, 2013 , vol. 135, # 7 p. 2552 - 2559
