potassium phosphate; (C5H5FeC5H3C(CH3)NC6H4CH3)PdCl(tricyclohexylphosphine); potassium acetate in 1,4-dioxane; water T=100°C; Suzuki coupling; 6 h; Inert atmosphere;

tetrakis(triphenylphosphine) palladium(0); sodium carbonate in ethanol; water; toluene Suzuki coupling; 24 h; RefluxInert atmosphere;

potassium phosphate; (C5H5FeC5H3C(CH3)NC6H4CH3)PdCl(tricyclohexylphosphine); potassium acetate in 1,4-dioxane; water T=100°C; Suzuki coupling; 15 h; Inert atmosphere;

dipotassium peroxodisulfate; [Rh(tetramethyl(trifluoromethyl)cyclopentadienyl)Cl2]2; para-toluenesulphonic acid silver salt in 2,2,2-trifluoroethanol T=74°C; Inert atmosphereSealed tube; regioselective reaction;

ammonia; cadmium calcium phosphate T=350 - 400°C; flow-type reactor;

1: N-allyl-N-tert-butoxycarbonyl-phenylethynylamine With N,N,N',N,-tetramethylethylenediamine; sec.-butyllithium in tetrahydrofuran T=-78°C; 1 h; Inert atmosphere; 2: methyl iodide With N,N,N',N',N'',N''-hexamethylphosphoric triamide in tetrahydrofuran T=-78°C; 1 h; Inert atmosphere; 3: With 3,4,5,6-tetrachloro-1,2-benzoquinone in acetic acid T=-78 - 20°C; 0.5 h;

palladium on activated charcoal T=300 - 310°C; 0.5 h;

1: 95 percent / H2 / Raney Ni / ethanol / 2 h / 80 °C / 72400.7 Torr 2: 70 percent / 10percent Pd/C / 0.5 h / 300 - 310 °C View Scheme

1: (C5H5FeC5H3C(CH3)NC6H4CH3)PdCl(tricyclohexylphosphine); potassium acetate / 1,4-dioxane / 2 h / 100 °C / Inert atmosphere 2: potassium phosphate; (C5H5FeC5H3C(CH3)NC6H4CH3)PdCl(tricyclohexylphosphine); potassium acetate / 1,4-dioxane; water / 6 h / 100 °C / Inert atmosphere View Scheme

1: (C5H5FeC5H3C(CH3)NC6H4CH3)PdCl(tricyclohexylphosphine); potassium acetate / 1,4-dioxane / 6 h / 100 °C / Inert atmosphere 2: potassium phosphate; (C5H5FeC5H3C(CH3)NC6H4CH3)PdCl(tricyclohexylphosphine); potassium acetate / 1,4-dioxane; water / 15 h / 100 °C / Inert atmosphere View Scheme