反应条件
(meso-tetrakis(2,3,5,6-tetrafluoro-4-N,N,N-trimethylaniliniumyl)porphyrin)iron(III) penta(trifluoromethylsulfonate) in further solvent(s) mixing solutions of NaClO2 and iron compd. and sodium phosphate (NaH2PO4, Na2HPO4) or ammonium acetate (CH3CO2NH4, NaOH) buffer in (18)OH2, pH 7.1, insufflation of N2 over the reaction head space at 2 ml/min by pump; gas analysis by mass spectrometry, soln. analysis by ion chromy. and ESImass spectrometry;
参考文献
Inorganic Chemistry, , vol. 48, # 5 p. 2260 - 2268
