in solid matrix Irradiation (UV/VIS); codeposition of NH3, O3, and Ar (Ar/NH3 = Ar/O3 = 300:1) at 10-14 K and photodissociation of the NH3-O3 complex in the Ar matrix by exposure to 290-1000 nm radiation; reaction studied by IR spectroscopy;
参考文献
Journal of Physical Chemistry, , vol. 92, # 8 p. 2155 - 2161
in solid matrix byproducts: (D2(18)O)2; Irradiation (UV/VIS); Hg evapd. from liq. at 50°C; codeposited with (18)O2 in excess D2onto CsI window at 5 K for 30 min; irradiated (mercury arc, > 220 nm) f or 42 min; monitored by IR spectra;
in solid matrix Irradiation (UV/VIS); Hg evapd. from liq. at 50°C; codeposited with D2 (2-8percent) and (18)O2 (0.2-2.0percent) in excess Ne onto CsI window at 5 K for 1 h; irradiated (mercury arc, > 220 nm) for 25 min; annealed to 12 K; monitored by IR spectra;
oxygen; platinum in neat (no solvent) Kinetics; byproducts: H2O, N2O, (15)NNO; UHV chamber with (15)NH3 as reducing agent between 428 and 475K and pressures between 1.5E-6 and 6E-5 torr); further byproduct: (15)N2O; not isolated, product ratio determined by mass spectrometry;
参考文献
van Tol; Siera; Cobden; Nieuwenhuys
Surface Science, 1992 , vol. 274, # 1 p. 63 - 81
[Mn4O6(N,N-bis(2-pyridylmethyl)ethylamine)4](ClO4)3 in water; acetonitrile byproducts: H2O; Electrolysis; at 22°C; bulk electrolysis; MAS; video recording displacement of mineral oil in gas buret;
参考文献
Angewandte Chemie - International Edition, , vol. 39, # 12 p. 2169 - 2172
