in gaseous matrix
Tesla coil discharge in (16)O2/(18)O2/Ar mixt.; O3 trapping at liq. N2 temp.;
参考文献
Valentini, James J.; Gerrity, Daniel P.; Phillips, David L.; Nieh, Jong-Chen; Tabor, Kevin D.
Journal of Chemical Physics, 1987 , vol. 86, # 12 p. 6745 - 6756
O2 in neat (no solvent, gas phase)
Kinetics; Electric Arc; electric discharge, natural O2 with 3percent (18)O2, 100 Torr; high enhancement ozone generated in vessel at room temp., cryogenically seperated; low enhancement ozone produced and collected at 77 K in pyrex vessel; further products; ratio of products detected by mass spectroscopy;
参考文献
Anderson, S. M.; Morton, J.; Mauersberger, K.
Chemical Physics Letters, 1989 , vol. 156, p. 175 - 180
electron in gaseous matrix
Irradiation (UV/VIS); 1064 nm Nd:YAG laser focusing on Ni or Cu target, metal atoms and electrons with 0.2percent O2/Ne codeposition for 2-6 h onto 4 K substrate, accordingto T. R. Burkholder, L. Andrews, J. Chem. Phys. 95 (1991) 8697;
参考文献
Zhou, Mingfei; Hacaloglu, Jale; Andrews, Lester
Journal of Chemical Physics, 1999 , vol. 110, # 19 p. 9450 - 9456
electron in gaseous matrix
Irradiation (UV/VIS); 1064 nm Nd:YAG laser focusing on Ni or Cu target, metal atoms and electrons with 0.2percent O2/Ne codeposition for 2-6 h onto 4 K substrate, accordingto T. R. Burkholder, L. Andrews, J. Chem. Phys. 95 (1991) 8697;
参考文献
Zhou, Mingfei; Hacaloglu, Jale; Andrews, Lester
Journal of Chemical Physics, 1999 , vol. 110, # 19 p. 9450 - 9456
in gaseous matrix
Irradiation (UV/VIS); rotating metal target irradiation with Nd:YAG laser (1064 nm, 10 Hz, 10 ns, 40-50 mJ/pulse), metal atoms codeposition with 0.5percent (16)O2/0.5percent (18)O2/Ar at 2-4 mmol/h for 1-3 h at 10 K, eventual annealing up to 35 K;
参考文献
Chertihin, George V.; Bare, William D.; Andrews, Lester
Journal of Chemical Physics, 1997 , vol. 107, # 8 p. 2798 - 2806
→
反应条件
in gaseous matrix
Irradiation (UV/VIS); rotating metal target irradiation with Nd:YAG laser (1064 nm, 10 Hz, 10 ns, 40-50 mJ/pulse), metal atoms codeposition with 0.5percent (16)O2/0.5percent (18)O2/0.5percent (16)O(18)O/Ar at 2-4 mmol/h for 1-3 h at 10 K, eventual annealing up to 35 K;
参考文献
Chertihin, George V.; Bare, William D.; Andrews, Lester
Journal of Chemical Physics, 1997 , vol. 107, # 8 p. 2798 - 2806
→
反应条件
oxygen in toluene
Kinetics; byproducts: dibenzyl, benzyl cyanide; stirring of the Ni compd. in toluene under O2 under atmospheric pressure for 2000-5000 sec.; identification of the products by GC analysis and IR;
