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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
4-氯乙酰乙酸甲酯
合成路线
（共 50 条）
32807-28-6
4-氯乙酰乙酸甲酯
→
反应条件
88496-70-2
(R)-4-氯-3-羟基丁酸甲酯
反应条件
Vigna unguiculata powder in water; isopropyl alcohol T=30°C; 48 h; optical yield given as percent eeenantioselective reaction;
参考文献
Bizerra, Ayla M.C.; Gonzalo, Gonzalo de; Lavandera, Ivan; Gotor-Fernandez, Vicente; de Mattos, Marcos Carlos; de Oliveira, Maria da Conceicao F.; Lemos, Telma L.G.; Gotor, Vicente
Tetrahedron Asymmetry, 2010 , vol. 21, # 5 p. 566 - 570
4128-31-8
仲辛醇
+
32807-28-6
4-氯乙酰乙酸甲酯
→
反应条件
5978-70-1
(R)-(-)-2-辛醇
+
88496-70-2
(R)-4-氯-3-羟基丁酸甲酯
反应条件
Tris-HCl buffer T=30°C; pH=7.5; 24 h; Enzymatic reaction; enantioselective reaction;
参考文献
Bisogno, Fabricio R.; Lavandera, Ivan; Kroutil, Wolfgang; Gotor, Vicente
Journal of Organic Chemistry, 2009 , vol. 74, # 4 p. 1730 - 1732
773837-37-9
+
32807-28-6
4-氯乙酰乙酸甲酯
→
反应条件
88496-70-2
(R)-4-氯-3-羟基丁酸甲酯
+
150966-86-2
反应条件
1: methyl-4-chloroacetoacetate With isopropyl alcohol T=30°C; pH=7.5; 4 h; aq. bufferEnzymatic reaction; 2: sodium cyanide With halohydrin dehalogenase from Agrobacterium radiobacter AD1 T=30°C; pH=7.5; 44 h; aq. bufferEnzymatic reaction; optical yield given as percent ee;
参考文献
European Journal of Organic Chemistry, , # 14 p. 2293 - 2298
32807-28-6
4-氯乙酰乙酸甲酯
→
反应条件
88496-70-2
(R)-4-氯-3-羟基丁酸甲酯
+
109462-42-2
反应条件
1: With isopropyl alcohol T=30°C; 4 h; aq. bufferEnzymatic reaction; 2: With Agrobacterium radiobacter AD1 halohydrin dehalogenase HheC T=30°C; 20 h; aq. bufferEnzymatic reaction; optical yield given as percent eestereoselective reaction;
参考文献
Tetrahedron Asymmetry, , vol. 20, # 4 p. 483 - 488
32807-28-6
4-氯乙酰乙酸甲酯
+
67-63-0
异丙醇
→
反应条件
88496-70-2
(R)-4-氯-3-羟基丁酸甲酯
+
67-64-1
丙酮
反应条件
Lactobacillus brevis dehydrogenase; NADPH; tris(hydroxymethyl)methylamine hydrochloride in water; dimethyl sulfoxide T=30°C; Enzymatic reaction; Kinetics;
参考文献
Bisogno, Fabricio R.; Garcia-Urdiales, Eduardo; Valdes, Haydee; Lavandera, Ivan; Kroutil, Wolfgang; Suarez, Dimas; Gotor, Vicente
Chemistry - A European Journal, 2010 , vol. 16, # 36 p. 11012 - 11019
4128-31-8
仲辛醇
+
32807-28-6
4-氯乙酰乙酸甲酯
→
反应条件
6169-06-8
(S)-(+)-2-辛醇
+
86728-93-0
(S)-4-氯-3-羟基丁酸甲酯
反应条件
Tris-HCl buffer T=30°C; pH=7.5; 24 h; Enzymatic reaction; enantioselective reaction;
参考文献
Bisogno, Fabricio R.; Lavandera, Ivan; Kroutil, Wolfgang; Gotor, Vicente
Journal of Organic Chemistry, 2009 , vol. 74, # 4 p. 1730 - 1732
32807-28-6
4-氯乙酰乙酸甲酯
→
反应条件
6289-46-9
2,5-二甲氧酰基-1,4-环己二酮
+
261963-22-8
反应条件
potassium iodide in N,N-dimethyl-formamide T=20°C; Condensation; esterification; cyclisation; 5 h;
参考文献
Segat-Dioury, Fabienne; Lingibe, Olivier; Graffe, Bernadette; Sacquet, Marie-Claude; Lhommet, Gerard
Tetrahedron, 2000 , vol. 56, # 2 p. 233 - 248
32807-28-6
4-氯乙酰乙酸甲酯
→
反应条件
17609-52-8
+
6289-46-9
2,5-二甲氧酰基-1,4-环己二酮
反应条件
in N,N-dimethyl-formamide Ambient temperature;
参考文献
Segat, Fabienne; Lingibe, Olivier; Graffe, Bernadette; Sacquet, Marie-Claude; Lhommet, Gerard
Heterocycles, 1997 , vol. 45, # 8 p. 1451 - 1455
32807-28-6
4-氯乙酰乙酸甲酯
+
67-63-0
异丙醇
→
反应条件
532-27-4
+
127-00-4
反应条件
Lactobacillus brevis dehydrogenase; NADPH; tris(hydroxymethyl)methylamine hydrochloride; magnesium chloride in water T=30°C; pH=7.5; 24 h; Enzymatic reaction;
参考文献
Chemistry - A European Journal, , vol. 16, # 36 p. 11012 - 11019
4630-06-2
+
32807-28-6
4-氯乙酰乙酸甲酯
→
反应条件
58917-26-3
+
86728-93-0
(S)-4-氯-3-羟基丁酸甲酯
反应条件
Tris-HCl buffer T=30°C; pH=7.5; 24 h; Enzymatic reaction; enantioselective reaction;
参考文献
Bisogno, Fabricio R.; Lavandera, Ivan; Kroutil, Wolfgang; Gotor, Vicente
Journal of Organic Chemistry, 2009 , vol. 74, # 4 p. 1730 - 1732
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