2-二氮杂-1-苯乙酮合成路线 （共 259 条）
反应条件
tetrabutyl ammonium fluoride in tetrahydrofuran
T=20°C; 4 h; Inert atmosphere;
参考文献
Wang, Chiou-Dong; Liu, Rai-Shung
Organic and Biomolecular Chemistry, 2012 , vol. 10, # 45 p. 8948 - 8952,5
反应条件
tetrabutyl ammonium fluoride; copper(I) bromide in tetrahydrofuran; dichloromethane
T=20°C; 4 h; Inert atmosphere;
参考文献
Wang, Chiou-Dong; Liu, Rai-Shung
Organic and Biomolecular Chemistry, 2012 , vol. 10, # 45 p. 8948 - 8952,5
反应条件
1: tetrahydrofuran / 1 h / 20 °C / Inert atmosphere
2: pyridinium chlorochromate / dichloromethane / 4 h / 0 - 20 °C / Inert atmosphere; Molecular sieve
View Scheme
参考文献
Sanchez-Carmona, Miguel A.; Contreras-Cruz, David A.; Miranda, Luis D.
Organic and Biomolecular Chemistry, 2011 , vol. 9, # 19 p. 6506 - 6508
反应条件
rhodium(II) octanoate in 1,2-dichloro-ethane; toluene
T=80°C; 0.5 h;
参考文献
Lee, Sang-Hyeup; Yoshida, Kazuhiro; Matsushita, Hana; Clapham, Bruce; Koch, Guido; Zimmermann, Juerg; Janda, Kim D.
Journal of Organic Chemistry, 2004 , vol. 69, # 25 p. 8829 - 8835
反应条件
in benzene
3 h; Heating; Yields of byproduct given;
参考文献
Andreichikov, Yu.S.; Gein, L.F.; Gein, V.L.
Journal of Organic Chemistry USSR (English Translation), 1981 , vol. 17, p. 545 - 550
Zhurnal Organicheskoi Khimii, 1981 , vol. 17, # 3 p. 631 - 637
参考文献
Wolff
Justus Liebigs Annalen der Chemie, 1912 , vol. 394, p. 44
参考文献
King; Miller
Journal of the American Chemical Society, 1948 , vol. 70, p. 4154
反应条件
1: CH2Cl2 / -70 °C
2: CH2Cl2 / 2 h / Ambient temperature
View Scheme
参考文献
Lorenz, Wolfgang; Maas, Gerhard
Journal of Organic Chemistry, 1987 , vol. 52, # 3 p. 375 - 381
反应条件
in liquid sulphur dioxide
参考文献
Vedejs,E. et al.
Journal of Organic Chemistry, 1977 , vol. 42, p. 3109 - 3113
反应条件
1: 93 percent / BF3*Et2O / diethyl ether / Ambient temperature
2: 99 percent / triethylamine / dimethylformamide / Heating
3: 1.) H2O, p-toluenesulfonic acid, 2.) periodic acid / 1.) CH3OH, reflux, 1 h, 2.) CH3OH, RT, 40 min
View Scheme
参考文献
Kachinsky, Joseph L. C.; Salomon, Robert G.
Journal of Organic Chemistry, 1986 , vol. 51, # 9 p. 1393 - 1401
