potassium hydroxide in methanol Heating;

1: N-bromosuccinimide, benzoyl peroxide / CCl4 / 28 h / Heating 2: 5 h / Heating 3: 83 percent / NaH / 1,2-dimethoxy-ethane / 2 h / Heating 4: 82 percent / H2, morpholine / 5 percent Rh/C / ethanol; methanol / 4 h / 18100.2 Torr / Ambient temperature 5: 81 percent / HCOONa / 3 h / Heating 6: K2CO3, Cu, CuBr / dimethylsulfoxide / 3 h / 160 °C 7: 5 N aq. NaOH / dimethylsulfoxide / 0.5 h / 75 °C View Scheme

1: 5 h / Heating 2: 83 percent / NaH / 1,2-dimethoxy-ethane / 2 h / Heating 3: 82 percent / H2, morpholine / 5 percent Rh/C / ethanol; methanol / 4 h / 18100.2 Torr / Ambient temperature 4: 81 percent / HCOONa / 3 h / Heating 5: K2CO3, Cu, CuBr / dimethylsulfoxide / 3 h / 160 °C 6: 5 N aq. NaOH / dimethylsulfoxide / 0.5 h / 75 °C View Scheme

1: 83 percent / NaH / 1,2-dimethoxy-ethane / 2 h / Heating 2: 82 percent / H2, morpholine / 5 percent Rh/C / ethanol; methanol / 4 h / 18100.2 Torr / Ambient temperature 3: 81 percent / HCOONa / 3 h / Heating 4: K2CO3, Cu, CuBr / dimethylsulfoxide / 3 h / 160 °C 5: 5 N aq. NaOH / dimethylsulfoxide / 0.5 h / 75 °C View Scheme

1: 85 percent / isoamyl nitrite, CuCl2 / acetonitrile / Ambient temperature 2: 95 percent / KOH / methanol / Heating View Scheme

horseradish peroxidase type VI; dihydrogen peroxide in water T=25°C; 11 h; Enzymatic reaction;

Mo2((1)-H)2(OtBu)6; (Ph)2SiH2 in toluene T=111°C; 25 h; Inert atmosphereSchlenk technique;

1: 81 percent / HCOONa / 3 h / Heating 2: K2CO3, Cu, CuBr / dimethylsulfoxide / 3 h / 160 °C 3: 5 N aq. NaOH / dimethylsulfoxide / 0.5 h / 75 °C View Scheme

1: K2CO3, Cu, CuBr / dimethylsulfoxide / 3 h / 160 °C 2: 5 N aq. NaOH / dimethylsulfoxide / 0.5 h / 75 °C View Scheme

1: Fremy’s salt; disodium hydrogen phosphate dodecahydrate / acetone; water / 0.5 h 2: sodium dithionite / water; dichloromethane / 0.17 h View Scheme