3-苯基-1-丙基硼酸频哪酯合成路线 （共 24 条）
反应条件
1: t-BuLi / toluene; pentane / 15 h / -78 - 20 °C 2: n-BuLi / tetrahydrofuran; hexane / 15 h / -78 - 20 °C View Scheme
参考文献
Journal of the American Chemical Society, , vol. 129, # 11 p. 3068 - 3069
反应条件
copper(l) iodide; tributylphosphine; lithium tert-butylate in N,N-dimethyl-formamide T=60°C; 24 h; Inert atmosphere;
参考文献
Angewandte Chemie - International Edition, , vol. 51, # 2 p. 528 - 532
反应条件
1: 4-methyl-N'-(3-phenylpropylidene)benzenesulfonohydrazide With sodium methylate; N-benzyl-N,N,N-trimethyl-ammonium chloride in toluene T=20°C; 1 h; Inert atmosphere; 2: 4,4,5,5-tetramethyl-[1,3,2]dioxaborolane in toluene T=90°C; Inert atmosphere;
参考文献
Li, Huan; Wang, Long; Zhang, Yan; Wang, Jianbo
Angewandte Chemie - International Edition, 2012 , vol. 51, # 12 p. 2943 - 2946
反应条件
[Rh(COD)(DPPB)]BF4*THF in further solvent(s) (N2); treatment of allylbenzene with pinacol borane in dichloroethane at30°C in presence of rhodium compd. and perfluorophenylborane for 24 h; GC anal.;
参考文献
Journal of the American Chemical Society, , vol. 132, # 1 p. 131 - 137
反应条件
sodium methylate in methanol; toluene T=110°C; 12 h; Inert atmosphere;
参考文献
Li, Huan; Wang, Long; Zhang, Yan; Wang, Jianbo
Angewandte Chemie - International Edition, 2012 , vol. 51, # 12 p. 2943 - 2946
反应条件
sodium methylate in methanol; toluene T=90°C; Inert atmosphere;
参考文献
Li, Huan; Wang, Long; Zhang, Yan; Wang, Jianbo
Angewandte Chemie - International Edition, 2012 , vol. 51, # 12 p. 2943 - 2946
反应条件
NiI2*3.5H2O; C5H5N; Zn in further solvent(s) in 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone in the presence ofNiI2*3.5H2O, C5H5N, NaI and Zn dust; heated at 60°C under air;
参考文献
Everson, Daniel A.; Jones, Brittany A.; Weix, Daniel J.
Journal of the American Chemical Society, 2012 , vol. 134, # 14 p. 6146 - 6159
反应条件
pyridine; N,N'-dimethyl-N,N'-propyleneurea; 4,4'-dimethoxy-2,2'-bipyridine; NiI2*3.5H2O; sodium iodide; zinc T=20 - 60°C; 5 h; chemoselective reaction;
参考文献
Everson, Daniel A.; Jones, Brittany A.; Weix, Daniel J.
Journal of the American Chemical Society, 2012 , vol. 134, # 14 p. 6146 - 6159
反应条件
NiI2; potassium methanolate; 2,6-bis[(4S)-isopropyl-2-oxazolin-2-yl]pyridine in 1-methyl-pyrrolidin-2-one Reagent/catalyst;
参考文献
Chemical Science, , vol. 4, # 10 p. 4022 - 4029
反应条件
1.1: methanol / 70 °C / Inert atmosphere 2.1: sodium methylate; N-benzyl-N,N,N-trimethyl-ammonium chloride / toluene / 1 h / 20 °C / Inert atmosphere 2.2: 90 °C / Inert atmosphere View Scheme
参考文献
Angewandte Chemie - International Edition, , vol. 51, # 12 p. 2943 - 2946
