反应条件
1: acetone / 24 h / 90 °C 2: di-μ-chloro-bis(η4-1,5-cyclooctadiene)diiridium; hydrogen; (Rax,S,S)-C3*-TunePhos / dichloromethane; tetrahydrofuran / 20 h / 30 °C / 31029.7 Torr / |Autoclave; |Glovebox 3: hydrogen; hydrogenchloride; 5 palladium on charcoal / ethanol; ethyl acetate / 24 h / 20 °C / 760.05 Torr / |Schlenk technique View Scheme
参考文献
Ye, Zhi-Shi; Guo, Ran-Ning; Cai, Xian-Feng; Chen, Mu-Wang; Shi, Lei; Zhou, Yong-Gui
Angewandte Chemie - International Edition, 2013 , vol. 52, # 13 p. 3685 - 3689
Angew. Chem., 2013 , vol. 125, # 13 p. 3773 - 3777,5
