8-甲基-1,4-二氧杂螺[4.5]癸-7-烯合成路线 （共 2 条）
反应条件
1: 98 percent / peroxybenzoic acid / CHCl3; diethyl ether / 20 h / 0 °C
2: 66 percent / lithium perchlorate / benzene / 4 h / Heating
View Scheme
参考文献
Burge, Geoffrey L.; Collins, David J.; Reitze, John D.
Australian Journal of Chemistry, 1982 , vol. 35, p. 1913 - 1925
反应条件
1: 98 percent / peroxybenzoic acid / CHCl3; diethyl ether / 20 h / 0 °C
2: 66 percent / lithium perchlorate / benzene / 4 h / Heating
3: 89 percent / diethyl ether / 1.) -20 deg C, 15 min, 2.) -5 deg C, 4 h
4: potassium hydrogen sulfate / 0.17 h / 150 °C
View Scheme
参考文献
Burge, Geoffrey L.; Collins, David J.; Reitze, John D.
Australian Journal of Chemistry, 1982 , vol. 35, p. 1913 - 1925
