7,8-二氮杂双环[2.2.2]辛-7-烯合成路线 （共 17 条）
反应条件
benzophenone; oxygen in monofluoro-trichloromethane T=-20°C; P=7600 Torr; 8 h; Irradiationoxygen trapping of the intermediate triplet biradical 1,4-cyclohexadiyl; Mechanism;
参考文献
Journal of the American Chemical Society, , vol. 106, p. 7646 - 7647
反应条件
in various solvent(s) T=230.1°C; other temperature, ΔH<*>, ΔS<*>, ΔG<*>; heat of decomposition; thermolysis of 2,3-diazabicyclo<2.2.2>oct-2-ene derivatives, effect of bridgehead substituents; Rate constantThermodynamic data;
参考文献
Engel, Paul S.; Nalepa, Christopher J.; Horsey, Douglas W.; Keys, Dalen E.; Grow, Robert T.
Journal of the American Chemical Society, 1983 , vol. 105, # 24 p. 7102 - 7107
反应条件
Oxonereg; in water
168 h; Heating;
参考文献
Greer, Melinda L.; Sarker, Haripada; Mendicino, Maria E.; Blackstock, Silas C.
Journal of the American Chemical Society, 1995 , vol. 117, # 42 p. 10460 - 10467
反应条件
2,6-di-tert-butyl-pyridine in acetonitrile
T=25°C; further cation radical reagent; novel oxaditive azoalkane reaction; Product distributionMechanism;
参考文献
Engel, Paul S.; Hoque, A. K. M. M.; Scholz, John N.; Shine, Henry J.; Whitmire, Kenton H.
Journal of the American Chemical Society, 1988 , vol. 110, # 23 p. 7880 - 7882
反应条件
2,6-di-tert-butyl-pyridine in acetonitrile
T=25°C; further cation radical reagent; novel oxaditive azoalkane reaction; Product distributionMechanism;
参考文献
Engel, Paul S.; Hoque, A. K. M. M.; Scholz, John N.; Shine, Henry J.; Whitmire, Kenton H.
Journal of the American Chemical Society, 1988 , vol. 110, # 23 p. 7880 - 7882
反应条件
1.1: tetrahydrofuran; cyclohexane; diethyl ether / 1.5 h / -78 - 20 °C
1.2: I2 / tetrahydrofuran; cyclohexane; diethyl ether / 20 °C
2.1: 0.80 g / pentane; cyclohexane; diethyl ether / 5 h / 0 - 20 °C
View Scheme
参考文献
Lockard, Jenny V.; Zink, Jeffrey I.; Trieber II, Dwight A.; Konradsson, Asgeir E.; Weaver, Michael N.; Nelsen, Stephen F.
Journal of Physical Chemistry A, 2005 , vol. 109, # 6 p. 1205 - 1215
反应条件
benzophenone; oxygen in monofluoro-trichloromethane
T=-20°C; P=7600 Torr; 8 h; Irradiationoxygen trapping of the intermediate triplet biradical 1,4-cyclohexadiyl; Mechanism;
参考文献
Adam, Waldemar; Hannemann, Klaus; Wilson, R. Marshall
Journal of the American Chemical Society, 1984 , vol. 106, p. 7646 - 7647
