醋酸(E)-11-十四烯酯合成路线 （共 62 条）
反应条件
1.1: lithium aluminium tetrahydride / diethyl ether / 3 h / 0 - 20 °C / Inert atmosphere 1.2: 0.5 h / 0 °C 2.1: bromine; triphenylphosphine / chloroform / 3 h / 20 °C / Inert atmosphere 3.1: magnesium / tetrahydrofuran 3.2: 9 h / 2 - 20 °C / Inert atmosphere 4.1: methanol; toluene-4-sulfonic acid / 24 h / 20 °C 5.1: pyridine / 24 h / 20 °C View Scheme
参考文献
Shakhmaev; Ishbaeva; Shayakhmetova
Russian Journal of General Chemistry, 2009 , vol. 79, # 6 p. 1171 - 1174
反应条件
in acetic acid T=50°C; 10 h; Yield given;
参考文献
Oprean, I.; Ciupe, Hilke; Gansca, Lucia; Hodosan, F.
Journal fuer Praktische Chemie (Leipzig), 1987 , vol. 329, # 2 p. 283 - 289
反应条件
1: 71 percent / tetrahydrofuran / -79 °C 2: acetic acid / 80 °C View Scheme
参考文献
Macdonald, Timothy L.; Narayanan, Amirthalingam B.; O'Dell, Dale E.
Journal of Organic Chemistry, 1981 , vol. 46, # 7 p. 1504 - 1506
反应条件
K(iPrO)3BH; thexylchloroborane*methyl sulfide; sodium methylate; acetic acid Yield given. Multistep reaction;
参考文献
Brown, Herbert C.; Lee, Hsiupu D.; Kulkarni, Surendra U.
Journal of Organic Chemistry, 1986 , vol. 51, # 26 p. 5282 - 5286
反应条件
aluminium trichloride; iodine; palladium 1.) CH2Cl2, 0 gradC, 1h. 2.) THF; Multistep reaction;
参考文献
Chan, T. H.; Koumaglo, K.
Tetrahedron Letters, 1986 , vol. 27, # 8 p. 883 - 886
反应条件
(i) MCPBA, (ii) Ph3PBr2, (iii) Zn, AcOH; Multistep reaction;
参考文献
Sonnet,P.E.; Oliver,J.E.
Journal of Organic Chemistry, 1976 , vol. 41, # 20 p. 3279 - 3283
反应条件
Cl2Ni(1,2-bis(diphenylphosphino)ethane) 1.) ether, 12 h, room temp., 2.) 80 deg C, 15 h; Yield given. Multistep reaction;
参考文献
Fiandanese, Vito; Marchese, Giuseppe; Naso, Francesco; Ronzini, Ludovico
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1985 , p. 1115 - 1120
反应条件
Yield given. Multistep reaction;
参考文献
Odinokov, V. N.; Ishmuratov, G. Yu.; Galeeva, R. I.; Kharisov, R. Ya.; Sokol'skaya, O. V.; at al.
Journal of Organic Chemistry USSR (English Translation), 1988 , vol. 24, # 4 p. 646 - 651
Zhurnal Organicheskoi Khimii, 1988 , vol. 24, # 4 p. 719 - 724
反应条件
1: 85 percent / 20percent aq. NaOH / aq. ethanol / 0.5 h / Ambient temperature 2: 97 percent / chlorine, dimethyl sulfide, triethylamine / CH2Cl2 / 0.25 h / -78 °C View Scheme
参考文献
Brown, Herbert C.; Lee, Hsiupu D.; Kulkarni, Surendra U.
Journal of Organic Chemistry, 1986 , vol. 51, # 26 p. 5282 - 5286
反应条件
sodium hydroxide in ethanol 0.5 h; Ambient temperature;
参考文献
Brown, Herbert C.; Lee, Hsiupu D.; Kulkarni, Surendra U.
Journal of Organic Chemistry, 1986 , vol. 51, # 26 p. 5282 - 5286
