2-氯-3-甲氧基苯甲酸合成路线 （共 21 条）
反应条件
1: With 2,2,6,6-tetramethylpiperidinyl-lithium in tetrahydrofuran T=0°C; 2 h; 2: With 1,2,2-trichloro-1,1,2-trichloro-ethane in tetrahydrofuran T=0 - 65°C; 2.5 h; 3: With hydrogenchloride T=20°C;
参考文献
Nguyen, Thi-Huu; Chau, Nguyet Trang Thanh; Castanet, Anne-Sophie; Nguyen, Kim Phi Phung; Mortier, Jacques
Journal of Organic Chemistry, 2007 , vol. 72, # 9 p. 3419 - 3429
反应条件
tetrabutylammomium bromide in N,N-dimethyl-formamide T=5°C; electrolysis (I=0.4 A); Yields of byproduct given;
参考文献
Heintz, Monique; Sock, Oumar; Saboureau, Christophe; Perichon, Jacques; Troupel, Michel
Tetrahedron, 1988 , vol. 44, # 6 p. 1631 - 1636
反应条件
1: (nitration) 2: H2 / Pd-C 3: (i) aq. HCl, NaNO2, (ii) CuCl, aq. HCl 4: aq. NaOH View Scheme
参考文献
Australian Journal of Chemistry, , vol. 29, p. 2003 - 2021
反应条件
1: H2 / Pd-C 2: (i) aq. HCl, NaNO2, (ii) CuCl, aq. HCl 3: aq. NaOH View Scheme
参考文献
Australian Journal of Chemistry, , vol. 29, p. 2003 - 2021
反应条件
potassium hydroxide T=60 - 70°C;
参考文献
Monatshefte fuer Chemie, , vol. 62, p. 178,184
反应条件
hydrogenchloride; ammonium hydroxide; sodium hydroxide; hydroxylamine hydrochloride; copper(II) sulfate; sodium nitrite Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Journal of Organic Chemistry, , vol. 59, # 11 p. 2939 - 2944
反应条件
potassium permanganate; water
参考文献
Journal of the Chemical Society, , p. 14,17
反应条件
hydrogenchloride; ammonium hydroxide; sodium disulfite; iron(III) chloride; copper(II) sulfate; sodium nitrite Multistep reaction. Title compound not separated from byproducts;
参考文献
Journal of Organic Chemistry, , vol. 59, # 11 p. 2939 - 2944
参考文献
Australian Journal of Chemistry, , vol. 29, p. 2003 - 2021
反应条件
1: tin (II)-chloride; hydrochloric acid 3: permanganate; alkali View Scheme
参考文献
Journal of the Chemical Society, , p. 1425
