3,6-二溴-9-乙基咔唑合成路线 （共 17 条）
反应条件
n-butyllithium in tetrahydrofuran
参考文献
Park, Minnie; Buck, Jason R.; Rizzo, Carmelo J.
Tetrahedron, 1998 , vol. 54, # 42 p. 12707 - 12714
反应条件
1: 3,6-dibromo-9-ethyl-9H-carbazole With n-butyllithium in tetrahydrofuran; hexane
T=-78°C; 2 h;
2: N,N-dimethyl-formamide in tetrahydrofuran; hexane
T=-78°C; 1 h; Further stages.;
参考文献
Kuhnert, Nikolai; Rossignolo, Giulia M.; Lopez-Periago, Ana
Organic and Biomolecular Chemistry, 2003 , vol. 1, # 7 p. 1157 - 1170
反应条件
tris-(dibenzylideneacetone)dipalladium(0); lithium hexamethyldisilazane; dicyclohexyl(2',6'-diisopropoxy-[1,1'-biphenyl]-2-yl)phosphine in tetrahydrofuran
T=65°C;
参考文献
Shen, Bo; Bedore, Matthew W.; Sniady, Adam; Jamison, Timothy F.
Chemical Communications, 2012 , vol. 48, # 60 p. 7444 - 7446
反应条件
1: 95 percent / triethylamine; PPh3; CuI / PdCl2(PPh3)2 / 10 h / Heating
2: 96 percent / KMnO4; CH3COOH / acetone / Heating
View Scheme
参考文献
Keshtov; Belomoina; Peregudov; Rusanov; Khokhlov
Doklady Chemistry, 2007 , vol. 412, # 1 p. 14 - 17
反应条件
copper(l) iodide; triethylamine; triphenylphosphine; bis-triphenylphosphine-palladium(II) chloride
10 h; Heating;
参考文献
Keshtov; Belomoina; Peregudov; Rusanov; Khokhlov
Doklady Chemistry, 2007 , vol. 412, # 1 p. 14 - 17
反应条件
n-butyllithium in tetrahydrofuran
T=-78 - 0°C;
参考文献
Park, Minnie; Buck, Jason R.; Rizzo, Carmelo J.
Tetrahedron, 1998 , vol. 54, # 42 p. 12707 - 12714
反应条件
[1,3-bis(diphenylphosphino) propane] dichloronickel(II) in diethyl ether
2 h; Heating;
参考文献
Park, Minnie; Buck, Jason R.; Rizzo, Carmelo J.
Tetrahedron, 1998 , vol. 54, # 42 p. 12707 - 12714
