(s)-1-苯基乙基氨基甲酸乙酯合成路线 （共 18 条）
反应条件
potassium carbonate in tetrahydrofuran 0 deg C, 2 h, then 25 deg C, 6 h;
参考文献
McQueney, Michael S.; Lee, Sheng-lian; Swartz, William H.; Ammon, Herman L.; Mariano, Patrick S.; Dunaway-Mariano, Debra
Journal of Organic Chemistry, 1991 , vol. 56, # 25 p. 7121 - 7130
反应条件
1: (E)-ethanone-1-phenyl-O-(phenylmethyl)oxime With borane-THF; enantiopure spiroborate ester in tetrahydrofuran T=25°C; 36 h; 2: chloroformic acid ethyl ester With 4-(N,N-dimethlyamino)pyridine; triethylamine in dichloromethane T=25°C; 3 h; Further stages. Title compound not separated from byproducts.;
参考文献
Huang, Xiaogen; Ortiz-Marciales, Margarita; Huang, Kun; Stepanenko, Viatcheslav; Merced, Francisco G.; Ayala, Angel M.; Correa, Wildeliz; De Jesus, Melvin
Organic Letters, 2007 , vol. 9, # 9 p. 1793 - 1795
反应条件
1: 94 percent / NaH / dimethylformamide / 20 °C 2: BH3*DMS / enantiopure spiroborate ester / tetrahydrofuran / 36 h / 25 °C 3: 0.150 g / DMAP; Et3N / CH2Cl2 / 3 h / 25 °C View Scheme
参考文献
Huang, Xiaogen; Ortiz-Marciales, Margarita; Huang, Kun; Stepanenko, Viatcheslav; Merced, Francisco G.; Ayala, Angel M.; Correa, Wildeliz; De Jesus, Melvin
Organic Letters, 2007 , vol. 9, # 9 p. 1793 - 1795
反应条件
1: BH3*DMS / enantiopure spiroborate ester / tetrahydrofuran / 36 h / 25 °C 2: 0.150 g / DMAP; Et3N / CH2Cl2 / 3 h / 25 °C View Scheme
参考文献
Huang, Xiaogen; Ortiz-Marciales, Margarita; Huang, Kun; Stepanenko, Viatcheslav; Merced, Francisco G.; Ayala, Angel M.; Correa, Wildeliz; De Jesus, Melvin
Organic Letters, 2007 , vol. 9, # 9 p. 1793 - 1795
反应条件
1: BH3*DMS / enantiopure spiroborate ester / tetrahydrofuran / 36 h / 25 °C 2: 0.150 g / DMAP; Et3N / CH2Cl2 / 3 h / 25 °C View Scheme
参考文献
Huang, Xiaogen; Ortiz-Marciales, Margarita; Huang, Kun; Stepanenko, Viatcheslav; Merced, Francisco G.; Ayala, Angel M.; Correa, Wildeliz; De Jesus, Melvin
Organic Letters, 2007 , vol. 9, # 9 p. 1793 - 1795
反应条件
1: BH3*DMS / enantiopure spiroborate ester / tetrahydrofuran / 36 h / 25 °C 2: 0.150 g / DMAP; Et3N / CH2Cl2 / 3 h / 25 °C View Scheme
参考文献
Huang, Xiaogen; Ortiz-Marciales, Margarita; Huang, Kun; Stepanenko, Viatcheslav; Merced, Francisco G.; Ayala, Angel M.; Correa, Wildeliz; De Jesus, Melvin
Organic Letters, 2007 , vol. 9, # 9 p. 1793 - 1795
反应条件
1: BH3*DMS / enantiopure spiroborate ester / tetrahydrofuran / 36 h / 25 °C 2: 0.150 g / DMAP; Et3N / CH2Cl2 / 3 h / 25 °C View Scheme
参考文献
Huang, Xiaogen; Ortiz-Marciales, Margarita; Huang, Kun; Stepanenko, Viatcheslav; Merced, Francisco G.; Ayala, Angel M.; Correa, Wildeliz; De Jesus, Melvin
Organic Letters, 2007 , vol. 9, # 9 p. 1793 - 1795
反应条件
1: BH3*DMS / enantiopure spiroborate ester / tetrahydrofuran / 36 h / 25 °C 2: 0.150 g / DMAP; Et3N / CH2Cl2 / 3 h / 25 °C View Scheme
参考文献
Huang, Xiaogen; Ortiz-Marciales, Margarita; Huang, Kun; Stepanenko, Viatcheslav; Merced, Francisco G.; Ayala, Angel M.; Correa, Wildeliz; De Jesus, Melvin
Organic Letters, 2007 , vol. 9, # 9 p. 1793 - 1795
反应条件
1: 1.) aq. Na2CO3 / 2.) CHCl3, 1 h, room t. 2: ethanol / 0.75 h / Heating View Scheme
参考文献
Schoenenberger, Bernhard; Brossi, Arnold; George, Clifford; Flippen-Anderson, Judith L.
Helvetica Chimica Acta, 1986 , vol. 69, p. 283 - 287
反应条件
sodium ethanolate in ethanol 1 h;
参考文献
Schoenenberger, Bernhard; Brossi, Arnold; George, Clifford; Flippen-Anderson, Judith L.
Helvetica Chimica Acta, 1986 , vol. 69, p. 283 - 287
