N,N-methylenediacrylamide; Cu(BF4)2*6H2O in water; dimethyl sulfoxide byproducts: MeC6H4CH2CH(SCN)CONHCH2NHCOCH(SCN)CH2C6H4Me; addn. of 2-MeC6H4N2BF4 (2.2 equiv.) to N,N-methylenediacrylamide (1 equiv.) , Cu(BF4)2*6H2O (0.1 equiv.) and KSCN (1.1 equiv.) in H2O-DMSO (1:4)for 45 min; evolution of gas at 10-15°C for 1 h;
参考文献
Grishchuk; Baranovskii; Gorbovoi; Ganushchak
Russian Journal of General Chemistry, 2003 , vol. 73, # 6 p. 957 - 960
N,N-methylenediacrylamide; Cu(BF4)2*6H2O in water; N,N-dimethyl-formamide byproducts: Cl2C6H3CH2CH(SCN)CONHCH2NHCOCH(SCN)CH2C6H3Cl2; addn. of 2,5-Cl2C6H3N2BF4 (2.2 equiv.) to N,N-methylenediacrylamide (1 equiv.), Cu(BF4)2*6H2O (0.1 equiv.) and KSCN (1.1 equiv.) in H2O-DMF (1:3) for 45 min; evolution of gas at 10-15°C for 1 h;
参考文献
Grishchuk; Baranovskii; Gorbovoi; Ganushchak
Russian Journal of General Chemistry, 2003 , vol. 73, # 6 p. 957 - 960
4-MeOC6H4CH2CH(SCN)CONHCH2NHCOCHCH2; Cu(BF4)2*6H2O in water; N,N-dimethyl-formamide byproducts: MeOC6H4CH2CH(SCN)CONHCH2NHCOCH(SCN)CH2C6H4OMe; addn. of 4-MeOC6H4N2BF4 to 4-MeOC6H4CH2CH(SCN)CONHCH2NHCOCHCH2, Cu(BF4)2*6H2O and KSCN in H2O-DMF (1:3) for 20 min; evolution of gas at 15-20°C for 45 min;
参考文献
Grishchuk; Baranovskii; Gorbovoi; Ganushchak
Russian Journal of General Chemistry, 2003 , vol. 73, # 6 p. 957 - 960
N,N-methylenediacrylamide; Cu(BF4)2*6H2O in water; dimethyl sulfoxide byproducts: C6H5CH2CH(SCN)CONHCH2NHCOCH(SCN)CH2C6H5; addn. of PhN2BF4 (2.2 equiv.) to N,N-methylenediacrylamide (1 equiv.), Cu(BF4)2*6H2O (0.1 equiv.) and KSCN (1.1 equiv.) in H2O-DMSO (1:4) for 45min; evolution of gas at 10-15°C for 1 h;
参考文献
Grishchuk; Baranovskii; Gorbovoi; Ganushchak
Russian Journal of General Chemistry, 2003 , vol. 73, # 6 p. 957 - 960
4-NO2C6H4CH2CH(SCN)CONHCH2NHCOCHCH2; Cu(BF4)2*6H2O in water; N,N-dimethyl-formamide byproducts: NO2C6H4CH2CH(SCN)CONHCH2NHCOCH(SCN)CH2C6H4NO2; addn. of 4-NO2C6H4N2BF4 to 4-NO2C6H4CH2CH(SCN)CONHCH2NHCOCHCH2, Cu(BF4)2*6H2O and KSCN in H2O-DMF (1:3) for 20 min; evolution of gas at 15-20°C for 45 min;
参考文献
Grishchuk; Baranovskii; Gorbovoi; Ganushchak
Russian Journal of General Chemistry, 2003 , vol. 73, # 6 p. 957 - 960
N,N-methylenediacrylamide; Cu(BF4)2*6H2O in water; dimethyl sulfoxide byproducts: MeC6H4CH2CH(SCN)CONHCH2NHCOCH(SCN)CH2C6H4Me; addn. of 4-MeC6H4N2BF4 (2.2 equiv.) to N,N-methylenediacrylamide (1 equiv.), Cu(BF4)2*6H2O (0.1 equiv.) and KSCN (1.1 equiv.) in H2O-DMSO (1:4) for 45 min; evolution of gas at 10-15°C for 1 h;
参考文献
Grishchuk; Baranovskii; Gorbovoi; Ganushchak
Russian Journal of General Chemistry, 2003 , vol. 73, # 6 p. 957 - 960
N,N-methylenediacrylamide; Cu(BF4)2*6H2O in water; dimethyl sulfoxide byproducts: MeC6H4CH2CH(SCN)CONHCH2NHCOCH(SCN)CH2C6H4Me; addn. of 3-MeC6H4N2BF4 (2.2 equiv.) to N,N-methylenediacrylamide (1 equiv.), Cu(BF4)2*6H2O (0.1 equiv.) and KSCN (1.1 equiv.) in H2O-DMSO (1:4) for 45 min; evolution of gas at 10-15°C for 1 h;
参考文献
Grishchuk; Baranovskii; Gorbovoi; Ganushchak
Russian Journal of General Chemistry, 2003 , vol. 73, # 6 p. 957 - 960
