1-溴-4-(三氟甲基硫代)苯合成路线 (共 14 条)
反应条件
1: p-bromophenyl mercaptan With sodium hydride in N,N-dimethyl-formamide T=20°C; Inert atmosphere; 2: perfluoromethyl iodide in N,N-dimethyl-formamide T=20°C; 14 h;
参考文献
Harsanyi, Antal; Dorko, Eva; Csapo, Agnes; Bako, Tibor; Peltz, Csaba; Rabai, Jozsef
Journal of Fluorine Chemistry, 2011 , vol. 132, # 12 p. 1241 - 1246
反应条件
potassium phosphate; 1,10-phenanthroline; copper(I) isothiocyanate; sulfur; silver carbonate in N,N-dimethyl-formamide T=130°C; 24 h; Inert atmosphereSealed tubeGlovebox;
参考文献
Zhai, Lijuan; Li, Yaming; Yin, Jun; Jin, Kun; Zhang, Rong; Fu, Xinmei; Duan, Chunying
Tetrahedron, 2013 , vol. 69, # 48 p. 10262 - 10266
反应条件
[2,2']bipyridinyl; [Cu(I)(CH3CN)4]PF6; potassium carbonate in diethylene glycol dimethyl ether T=35°C; Schlenk techniqueInert atmosphere;
参考文献
Shao, Xinxin; Wang, Xueqiang; Yang, Tao; Lu, Long; Shen, Qilong
Angewandte Chemie - International Edition, 2013 , vol. 52, # 12 p. 3457 - 3460
Angew. Chem., 2013 , vol. 125, # 12 p. 3541 - 3544,4
反应条件
potassium phosphate; 1,10-phenanthroline; copper(I) isothiocyanate; sulfur; silver carbonate in N,N-dimethyl-formamide T=20°C; 24 h; Molecular sieveInert atmosphere;
参考文献
Chen, Chao; Xie, Yan; Chu, Lingling; Wang, Ruo-Wen; Zhang, Xingang; Qing, Feng-Ling
Angewandte Chemie - International Edition, 2012 , vol. 51, # 10 p. 2492 - 2495
反应条件
XeF2 in dichloromethane T=-20 - 5°C;
参考文献
Sipyagin; Enshov; Kashtanov; Potemkin; Thrasher; Waterfeld
Russian Chemical Bulletin, 2004 , vol. 53, # 2 p. 420 - 434
反应条件
sulfur dioxide; N(Et)4ClO4 in pyridine; N,N-dimethyl-formamide electrolysis (Pt-electrodes); Yield given;
参考文献
Journal of Fluorine Chemistry, , vol. 70, # 2 p. 277 - 278
反应条件
hydrogen fluoride 200°C; hours;
参考文献
Journal of Organic Chemistry, , vol. 29, p. 898 - 900
参考文献
Zhurnal Obshchei Khimii, , vol. 24, p. 887
J. Gen. Chem. USSR (Engl. Transl.), , vol. 24, p. 885,886
反应条件
1: chloroform; chlorine / Sonnenlicht 2: antimony (III)-fluoride View Scheme
参考文献
Zhurnal Obshchei Khimii, , vol. 24, p. 887
J. Gen. Chem. USSR (Engl. Transl.), , vol. 24, p. 885,886
参考文献
Zhurnal Obshchei Khimii, , vol. 24, p. 887
J. Gen. Chem. USSR (Engl. Transl.), , vol. 24, p. 885,886