双(三环己基磷)钯(0)合成路线 （共 19 条）
反应条件
in tetrahydrofuran; THF-d8 (tetrahydrofuran-d8) T=100°C; P=760.051 Torr; 16 h; Inert atmosphere;
参考文献
Organometallics, , vol. 32, # 13 p. 3631 - 3639
反应条件
H2O in benzene-d6 a benzene-d6 soln. of the Pd-compd. in a NMR tube is injected with water; (31)P-NMR spectroscopy;
参考文献
Inorganic Chemistry, , vol. 30, p. 3371 - 3381
反应条件
lithium triethylborohydride in tetrahydrofuran treating 1 mmol of the complex in THF at -80°C with a 1 M THF soln. of LiB(C2H5)3H; storing for 4h; evaporation to dryness under reducedpressure;; extraction with toluene; pptn. by addn. of methanol; detn. by 31P NMR in CD3C6D5;;
参考文献
Inorganica Chimica Acta, , vol. 119, p. 19 - 24
反应条件
in toluene-d8 (Ar); std. Schlenk technique; Pd complex was reacted with PCy3 (2 equiv.) in toluene at 80°C for 3 h or at 100°C for 1 h;
参考文献
Organometallics, , vol. 28, # 23 p. 6732 - 6738
反应条件
1: toluene / 0.25 h / 50 °C / |Inert atmosphere 2: 4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl-4',4',5',5'-tetramethyl-1,3,2-dioxaborolane / toluene / 0.17 h / 70 °C / |Inert atmosphere View Scheme
参考文献
Angewandte Chemie - International Edition, , vol. 52, # 22 p. 5822 - 5826
Angew. Chem., , vol. 52, # 22 p. 5822 - 5826,5
反应条件
1: tetrahydrofuran; benzene View Scheme
参考文献
Inorganic Chemistry, , vol. 30, p. 3371 - 3381
反应条件
in 1,4-dioxane T=75°C; 1.5 h; Inert atmosphereSchlenk technique; SolventTemperatureTime;
参考文献
Organometallics, , vol. 32, # 1 p. 9 - 11
反应条件
in methanol (N2 or Ar); dropped a soln. of B-compound into a soln. of Pd-complex; pptd. after 0.5 h; allowed to stand for 2 h at room temp. and for 2 h at -78°C; filtered; dried in vacuo; IR, NMR;
参考文献
Organometallics, , vol. 10, p. 1038 - 1044
参考文献
Inorganic Chemistry, , vol. 30, p. 3371 - 3381
