9,9-二甲基芴-2-硼酸合成路线 （共 13 条）
反应条件
1: With n-butyllithium in tetrahydrofuran T=-78°C; 2: With boric acid trimethyl ester in tetrahydrofuran 0.5 h; 3: With hydrogenchloride; water in tetrahydrofuran T=20°C; 1 h;
参考文献
LG Chem, Ltd.
Patent: EP2343277 A2, 2011 ;
Location in patent: Page/Page column 35-36 ;
反应条件
1: 2-bromo-9,9-dimethyl-9H-fluorene With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 1 h; Inert atmosphereCooling with ethanol-dry ice; 2: boric acid trimethyl ester in tetrahydrofuran; hexane T=-78°C; 4 h; Inert atmosphere; 3: With hydrogenchloride in tetrahydrofuran; hexane T=0°C; 6 h;
参考文献
Huang, Hai-Fang; Xu, Shi-Hua; He, Yan-Bo; Zhu, Cai-Cai; Fan, He-Liang; Zhou, Xue-Hua; Gao, Xi-Cun; Dai, Yan-Feng
Dyes and Pigments, 2013 , vol. 96, # 3 p. 705 - 713
反应条件
1: With n-butyllithium; boric acid trimethyl ester in tetrahydrofuran; hexane T=-70°C; 2: With acidic aq. solution
参考文献
Tsuboyama, Akira; Iwawaki, Hironobu; Furugori, Manabu; Mukaide, Taihei; Kamatani, Jun; Igawa, Satoshi; Moriyama, Takashi; Miura, Seishi; Takiguchi, Takao; Okada, Shinjiro; Hoshino, Mikio; Ueno, Kazunori
Journal of the American Chemical Society, 2003 , vol. 125, # 42 p. 12971 - 12979
反应条件
n-butyllithium in not given
参考文献
Journal of the American Chemical Society, , vol. 125, # 42 p. 12971 - 12979
反应条件
1: 2-bromo-9,9-dimethyl-9H-fluorene With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 1 h; Inert atmosphere; 2: 2-isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane in tetrahydrofuran; hexane T=20°C; 12 h; Inert atmosphere;
参考文献
Bulletin of the Korean Chemical Society, , vol. 33, # 11 p. 3629 - 3634
反应条件
hydrogenchloride; water in tetrahydrofuran 4 h;
参考文献
Li, Chang-Shun; Tsai, Ya-Hsuan; Lee, Wei-Chen; Kuo, Wen-Jang
Journal of Organic Chemistry, 2010 , vol. 75, # 12 p. 4004 - 4013
反应条件
1: palladium diacetate / toluene; 1,4-dioxane; ethanol; water 2: triethyl phosphite View Scheme
参考文献
Jung, Su Jin; Kim, Won Sam; Park, Byung Sun; Lee, Jae Kyun; Park, Jung Hwan; Choi, Kihang; Lee, So Ha
Heteroatom Chemistry, 2013 , vol. 24, # 1 p. 18 - 24
反应条件
1: potassium carbonate / tetrakis(triphenylphosphine) palladium(0) / water; tetrahydrofuran / 24 h / Inert atmosphere; Reflux 2: triphenylphosphinepalladium / 1,2-dichloro-benzene / 24 h / Reflux View Scheme
参考文献
Duksan Hi-Metal Co., Ltd.
Patent: EP2415773 A2, 2012 ;
反应条件
1: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / toluene; ethanol; water / 6 h / 120 °C 2: triethyl phosphite / 1,2-dichloro-benzene / 20 h / 160 °C View Scheme
参考文献
ROHM AND HAAS ELECTRONIC MATERIALS KOREA LTD.; AHN, Hee-Choon; LEE, Hyo-Jung; LEE, Mi-Ja; YANG, Soo-Jin; KIM, Chi-Sik; LEE, Su-Hyun; KIM, Hee-Sook; SHIN, Hyo-Nim; PARK, Kyoung-Jin; LEE, Kyung-Joo; KWON, Hyuck-Joo; KIM, Bong-Ok
Patent: WO2013/122402 A1, 2013 ;
反应条件
sodium carbonate; tetrakis(triphenylphosphine) palladium(0) in water; toluene
T=90°C; 8 h;
参考文献
Shin, Hyo Nim; Kim, Chi Sik; Kwon, Hyuck Joo; Cho, Young Jung; Kim, Bong Ok; Kim, Sung Min; Yoon, Seung Soo
Patent: US2011/152587 A1, 2011 ;
Location in patent: Page/Page column 30-31 ;
