反应条件
1: 95 percent / PPTS
2: 1) Mg, 2) 0.1 M Li2CuCl4 / 1) THF, 2) below 5 deg C, 3 h; rt
3: p-toluenesulphonic acid / methanol / 4 h / Heating
4: 85 percent / PPh3Br2, pyridine / CH2Cl2; CCl4 / Ambient temperature
5: 1) Mg / 1) THF, 2) -70 deg C to room temperature, 2 h
6: 82 percent / m-chloroperbenzoic acid / CH2Cl2 / 0 - 5 °C
7: 64 percent / H5IO6 / tetrahydrofuran; diethyl ether / 2 h / 0 - 5 °C
8: 1) Mg / 1) THF, 2) 2 h, 0 deg C; room temperature
View Scheme
参考文献
Iyer, R. R.; Mamdapur, V. R.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1989 , vol. 28, # 1-11 p. 728 - 732
