(CD3COCD3)D(1+) in gas T=57.9°C; experiment conditions: NBS pulsed ion cyclotron resonance; probability of a reactive H/D exchange encounter for the deuteronated ion as a function of the Gibbs free-energy change of the (endoergic) deuteron transfer reaction; Rate constantMechanismThermodynamic data;

water-d2

T=45°C; 10 h; Irradiation; Product distribution;