2-苯基-2,3-二氢呋喃合成路线 (共 22 条)
反应条件
N-ethyl-N,N-diisopropylamine; triphenylphosphine; palladium diacetate in tetrahydrofuran; acetonitrile T=60°C; P=7500600 Torr; enantioselectivity with other pressure; Product distribution;
参考文献
Hillers, Stephan; Reiser, Oliver
Tetrahedron Letters, 1993 , vol. 34, # 33 p. 5265 - 5268
反应条件
4-benzyl-4-methylmorpholinium tetrafluoroborate; palladium diacetate; potassium carbonate in N,N-dimethyl-formamide T=70°C; Heck reaction; 2 h; Inert atmosphere; regioselective reaction;
参考文献
Roszak, Rafal; Trzeciak, Anna M.; Pernak, Juliusz; Borucka, Nina
Applied Catalysis A: General, 2011 , vol. 409-410, p. 148 - 155
反应条件
1: diethyl ether / -30 - 20 °C 2: Mo(CO)5*Et3N / diethyl ether / 72 h / 20 °C View Scheme
参考文献
Schmidt, Bernd; Kocienski, Philip; Reid, Gillian
Tetrahedron, 1996 , vol. 52, # 5 p. 1617 - 1630
反应条件
(R)-Xyl-SDP(O); N-ethyl-N,N-diisopropylamine; bis(dibenzylideneacetone)-palladium(0); 4-nitro-benzoic acid in ethylene glycol T=80°C; Heck Reaction; 6 h; Inert atmosphereGlovebox; Overall yield = 50 percentChromat.; enantioselective reaction;
参考文献
Wu, Chunlin; Zhou, Jianrong
Journal of the American Chemical Society, 2014 , vol. 136, # 2 p. 650 - 652
参考文献
Dana, Gilbert; Figadere, Bruno; Touboul, Estera
Tetrahedron Letters, 1985 , vol. 26, # 46 p. 5683 - 5684
反应条件
silver trifluoromethanesulfonate; triethylamine in tetrahydrofuran
参考文献
Hii, King Kuok; Claridge, Timothy D. W.; Brown, John M.
Angewandte Chemie (International Edition in English), 1997 , vol. 36, # 9 p. 984 - 987
反应条件
Pd(I)[((S)-BINAP)2(Ph)]; triethylamine in tetrahydrofuran T=40°C; Heck reaction; 22 h; Product distribution; Further Variations:ReagentsTemperatures;
参考文献
Hii; Claridge, Timothy D. W.; Brown, John M.; Smith, Andrew; Deeth, Robert J.
Helvetica Chimica Acta, 2001 , vol. 84, # 10 p. 3043 - 3056
反应条件
1: sodium acetate; palladium diacetate / acetonitrile / 0.25 h / 20 °C / Inert atmosphere 2: chloranil / acetonitrile / 20 h / 80 °C / Inert atmosphere View Scheme
参考文献
Schmidt, Bernd; Geissler, Diana
European Journal of Organic Chemistry, 2011 , # 25 p. 4814 - 4822
反应条件
hydrogenchloride; palladium diacetate; air; copper dichloride in acetonitrile 120 h; Ambient temperature;
参考文献
Tetrahedron, , vol. 52, # 31 p. 10405 - 10416
反应条件
n-butyllithium in tetrahydrofuran
T=25°C;
参考文献
Groh, Brian L.; Magrum, Glenn R.; Barton, Thomas J.
Journal of the American Chemical Society, 1987 , vol. 109, # 24 p. 7568 - 7569