1-叔丁基-3-甲氧基苯合成路线 （共 24 条）
反应条件
1: 1,1-dimethylethylmagnesium chloride With bis(acetylacetonate)nickel(II); lithium tert-butylate in tetrahydrofuran T=0°C; 0.166667 h; Inert atmosphere; 2: 3-methoxybromobenzene in tetrahydrofuran T=0 - 20°C; Kumada-Corriu-Tamao type reaction; Inert atmosphere;
参考文献
Lohre, Claudia; Droege, Thomas; Wang, Congyang; Glorius, Frank
Chemistry - A European Journal, 2011 , vol. 17, # 22 p. 6052 - 6055
反应条件
tetra-(n-butyl)ammonium iodide; sodium thiosulfate; methyloxirane in dichloromethane 12 h; Irradiation;
参考文献
Byers, Jeffrey H.; Neale, Nathan R.; Bradford Alexander; Gangemi, Stephen P.
Tetrahedron Letters, 2007 , vol. 48, # 44 p. 7903 - 7905
反应条件
1: thionyl chloride / 2 h / 0 °C / Inert atmosphere 2: hexane; dichloromethane / -78 - 25 °C View Scheme
参考文献
Hartsel, Joshua A.; Craft, Derek T.; Chen, Qiao-Hong; Ma, Ming; Carlier, Paul R.
Journal of Organic Chemistry, 2012 , vol. 77, # 7 p. 3127 - 3133
反应条件
1: tetrahydrofuran 2: thionyl chloride / 2 h / 0 °C / Inert atmosphere 3: hexane; dichloromethane / -78 - 25 °C View Scheme
参考文献
Hartsel, Joshua A.; Craft, Derek T.; Chen, Qiao-Hong; Ma, Ming; Carlier, Paul R.
Journal of Organic Chemistry, 2012 , vol. 77, # 7 p. 3127 - 3133
参考文献
Carpenter et al.
Journal of Organic Chemistry, 1951 , vol. 16, p. 586,606
反应条件
in hexane; dichloromethane T=-78 - 25°C;
参考文献
Hartsel, Joshua A.; Craft, Derek T.; Chen, Qiao-Hong; Ma, Ming; Carlier, Paul R.
Journal of Organic Chemistry, 2012 , vol. 77, # 7 p. 3127 - 3133
反应条件
(i) nBuLi, Me2NCH2CH2NMe2, cyclohexane, (ii) /BRN= 1900390/; Multistep reaction;
参考文献
Shirley,D.A. et al.
Journal of Organometallic Chemistry, 1974 , vol. 69, p. 327 - 344
反应条件
aluminium trichloride in neat (no solvent) T=80°C; time dependence of isomerization; Product distribution;
参考文献
Olah, George A.; Olah, Judith A.; Ohyama, Toshiyuki
Journal of the American Chemical Society, 1984 , vol. 106, # 18 p. 5284 - 5290
反应条件
RhH(CO)(triphenylphosphine)3; 1,2-bis-(diphenylphosphino)ethane T=130°C; 12 h; Inert atmosphere;
参考文献
Organic Letters, , vol. 14, # 3 p. 855 - 857
反应条件
aluminium trichloride in neat (no solvent)
T=80°C; time dependence of isomerization; Product distribution;
参考文献
Olah, George A.; Olah, Judith A.; Ohyama, Toshiyuki
Journal of the American Chemical Society, 1984 , vol. 106, # 18 p. 5284 - 5290
