in toluene
was heated at 70°C for 2h; was filtered; filtrate was concentrated under reduced pressure; was diluted with hexane; GLC;
参考文献
Fuchita, Yoshio; Hiraki, Katsuma; Kamogawa, Yasuko; Suenaga, Miho; Tohgoh, Kazutaka; Fujiwara, Yuzo
Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 4 p. 1081 - 1085
in toluene
was heated at 70°C for 2h; was filtered; filtrate was concentrated under reduced pressure; was diluted with hexane; GLC;
参考文献
Fuchita, Yoshio; Hiraki, Katsuma; Kamogawa, Yasuko; Suenaga, Miho; Tohgoh, Kazutaka; Fujiwara, Yuzo
Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 4 p. 1081 - 1085
in dimethyl sulfoxide
(Ar), Schlenk techniques; Pd(CH3CO2)2 and ylidene ligand dissolved in DMSO, stirred for 3 h at 50°C, heated to 90°C for 1 h; solvent removed under vac., residue stirred with THF, filtered, solvent evapd. under vac., recrystd. from THF; elem. anal.;
参考文献
Linninger, Claudia S.; Herdtweck, Eberhardt; Hoffmann, Stephan D.; Herrmann, Wolfgang A.; Kuehn, Fritz E.
Journal of Molecular Structure, 2008 , vol. 890, # 1-3 p. 192 - 197
in acetic acid
T=80°C; 20 h; α-Methylstyrene:Pd(OAc)2 ratio: 10:1. Effect of sodium acetate, α-methylstyrene:Pd(OAc)2 ratio, temperature and reaction time was investigated.; Product distribution;
参考文献
Norman, Richard O. C.; Thomas, C. Barry; Watson, Grenville
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1980 , p. 1099 - 1104
