反应条件
in neat (no solvent) byproducts: KOH, H2; the solid precursor KAsH2 (prepared from 99.995percent K and 99.9999percent As) is contained in a hermetically sealed stainless steel reaction vessel outfitted with mixing device, low pressure arsine gas is generated through controlled addn. of water;; AsH3 is pumped through a 3A molecular sieve trap and an arsine purifier cartridge to reduce water and oxygen;;
参考文献
Hummel, S. G.; Zou, Y.; Beyler, C. A.; Grodzinski, P.; Dapkus, P. D.; et al.
Applied Physics Letters, 1992 , vol. 60, p. 1483 - 1485